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Generation of singlet diatomic sulfur from 9, 10-epidithio-9, 10-dihydroanthracene

W Ando, H Sonobe, T Akasaka

文献索引:Ando, Wataru; Sonobe, Hideki; Akasaka, Takeshi Tetrahedron Letters, 1987 , vol. 28, # 52 p. 6653 - 6656

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被引用次数: 26

摘要

Summary: The novel 9, 10-epidithio-9, 10-dihydroanthracene(2a) was formed as an intermediate in the reaction of 9, 10-dihydro-9, 10-(1, 3-epixthio-2-methano-2-p- methoxyphenyl-1-oxide) propanoanthracene(3) with perchloric acid. Singlet diatomic sulfur was generated from endodisulfTde & and trapped with conjugated dienes.