Journal of Organometallic Chemistry

Preparation and reactions of the mono-and dialkali salts of dimethyl sulfone, dimethyl sulfoxide, and related compounds

EM Kaiser, RD Beard, CR Hauser

文献索引：Kaiser,E.M. et al. Journal of Organometallic Chemistry, 1973 , vol. 59, p. 53 - 64

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被引用次数: 1

摘要

Abstract Certain sulfones and sulfoxides are rapidly and conveniently converted to their novel 1, 3-dialkali salts which, in many cases, are stabilized only by the-SO 2-and-SO- groups, respectively. That such species are formed is demonstrated by subsequent synthetically useful double aldol-type condensations and alkylations, and, in a few cases, by deuterations. Profound metallic cation effects are observed in several of the aldol-type ...