Metalloporphyrin-catalyzed decomposition of ethyl azidoformate

M Mitani, M Takayama, K Koyama

文献索引：Mitani, Michiharu; Takayama, Mimatsu; Koyama, Kikuhiko Journal of Organic Chemistry, 1981 , vol. 46, # 11 p. 2226 - 2227

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被引用次数: 4

摘要

Ethyl azidoformate (2) was thermolyzed in the presence of metalloporphyrins. CoTPP accelerated the decomposition rate of 2 and resulted in the preferential formation of the hydrogen-abstraction product (urethane). On the other hand, NiTPP and CuTPP had no influence on the decomposition behavior of 2.