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Journal of the American Chemical Society

Neighboring Carbon and Hydrogen. XXXIX. 1 Complex Rearrangements of Bridged Ions. Rearrangement Leading to the Bird-cage Hydrocarbon1

L De Vries, S Winstein

文献索引:De Vries,L.; Winstein,S. Journal of the American Chemical Society, 1960 , vol. 82, p. 5363 - 5376

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被引用次数: 30

摘要

Results Materials.-The mixture of endo-and exoacetates I-OAc and 11-OAc is readily available from the Diels-Alder reaction between cyclopentadiene and vinyl a~ etate.~ The exo-endo-4a, 8a-fusion of the two bicycloheptane nuclei was deduced by Solo-way4 in an excellent analysis of the stereochemistry of fused norcamphane systems. The necessary plausible assumption that the configuration of the carbon skeleton of I and I1 is identical ...