The Journal of Organic Chemistry

Coordination Effects in Organic Reactions. I. A Novel Preparation of t-Alkyl Isocyanide Complexes by N-Alkylation of Hydrogen Cyanide

S Otsuka, K Mori, K Yamagami

文献索引：Otsuka,S. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 4170 - 4174

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被引用次数: 22

摘要

A reaction scheme is proposed to Scope of the novel alkylation reactions was studied and give t-butyl isocyanide cuprous complexes,[(CHa) aCNC] sCuX and (CH8) aCNC. CuCN. can be liberated from the cuprous complexes by aqueous potassium cyanide. explain the formation of these cuprous complexes. physical properties of a number of new t-alkyl isocyanides thus obtained were recorded.