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High temperature bromination Part XXIII: Bromination of octahydro-1H-indene and octahydro-1H-4, 7-methanoindene

MS Ozer, B Kilbas, M Balcia

文献索引:Ozer, Melek Sermin; Kilbas, Benan; Balci, Metin Arkivoc, 2013 , vol. 2013, # 4 p. 388 - 404

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摘要

Abstract Thermal and photobromination of octahydro-1H-indene and octahydro-1H-4, 7- methanoindene were investigated. Three isomeric tetrabromides (1, 3, 4, 7-tetrabromo-2, 3, 4, 5, 6, 7-hexahydro-1H-indene) were formed along with a smaller amount of tribromoindane and a pentabromide by thermal bromination of octahydro-1H-indene. The thermodynamically most stable isomers were formed. Morover, thermal and ...