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Journal of the American Chemical Society

A New Reaction of Nitriles. I. Amides from Alkenes and Mononitriles1

JJ Ritter, PP Minieri

文献索引:Ritter; Minieri Journal of the American Chemical Society, 1948 , vol. 70, p. 4045,4046

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被引用次数: 493

摘要

Summary Cyclohexene is isomerized over pure alumina at 470450 to methylcyclopentene-1 and-2. Methylcyclohexene-1 is isomerized over pure alumina to 1, 2-dimethyl-and ethyl- cyclopentenes as indicated in formulas V to VIII, inclusive. The four cyclopentenes have all been isolated in yields which make them available for synthesis. The method of oxidation using hydrogen peroxide in formic acid has been used quite effectively for the conversion ...