Summary Cyclohexene is isomerized over pure alumina at 470450 to methylcyclopentene-1 and-2. Methylcyclohexene-1 is isomerized over pure alumina to 1, 2-dimethyl-and ethyl- cyclopentenes as indicated in formulas V to VIII, inclusive. The four cyclopentenes have all been isolated in yields which make them available for synthesis. The method of oxidation using hydrogen peroxide in formic acid has been used quite effectively for the conversion ...