2-(Bromovinyl)Trimethylsilane

Modify Date: 2024-01-04 10:32:04

2-(Bromovinyl)Trimethylsilane Structure
2-(Bromovinyl)Trimethylsilane structure
Common Name 2-(Bromovinyl)Trimethylsilane
CAS Number 41309-43-7 Molecular Weight 179.13000
Density 1.167 g/mL at 25 °C(lit.) Boiling Point 50-51 °C52 mm Hg(lit.)
Molecular Formula C5H11BrSi Melting Point N/A
MSDS Chinese USA Flash Point 85 °F
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name 2-(Bromovinyl)Trimethylsilane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.167 g/mL at 25 °C(lit.)
Boiling Point 50-51 °C52 mm Hg(lit.)
Molecular Formula C5H11BrSi
Molecular Weight 179.13000
Flash Point 85 °F
Exact Mass 177.98100
LogP 2.77240
Index of Refraction n20/D 1.466(lit.)
Storage condition 2-8°C

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi
Risk Phrases 10-36/37/38
Safety Phrases 26
RIDADR UN 1993 3/PG 3
WGK Germany 3
HS Code 2931900090

 Synthetic Route

~74%

2-(Bromovinyl)Trimethylsilane Structure

2-(Bromovinyl)T...

CAS#:41309-43-7

Literature: Lang, Yunhui; Souza, Fabio E. S.; Xu, Xinshe; Taylor, Nicholas J.; Assoud, Abdeljalil; Rodrigo, Russell Journal of Organic Chemistry, 2009 , vol. 74, # 15 p. 5429 - 5439

~%

2-(Bromovinyl)Trimethylsilane Structure

2-(Bromovinyl)T...

CAS#:41309-43-7

Literature: Pillot,J.P. et al. Synthetic Communications, 1979 , vol. 9, p. 395 - 406

~%

2-(Bromovinyl)Trimethylsilane Structure

2-(Bromovinyl)T...

CAS#:41309-43-7

Literature: Pillot,J.P. et al. Synthetic Communications, 1979 , vol. 9, p. 395 - 406

~%

2-(Bromovinyl)Trimethylsilane Structure

2-(Bromovinyl)T...

CAS#:41309-43-7

Literature: Pillot,J.P. et al. Synthetic Communications, 1979 , vol. 9, p. 395 - 406

~%

2-(Bromovinyl)Trimethylsilane Structure

2-(Bromovinyl)T...

CAS#:41309-43-7

Literature: Mironow et al. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959 , p. 1954,1958;engl.Ausg.S.1864,1868 Full Text Show Details Mironow; Petrow Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1958 , p. 787; engl. Ausg. S. 767

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles3

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Palladium-Catalyzed Cross-Coupling Syntheses of Benzotriazolyl Enynes and a General Route to Enynyl Ketones and Alkynyl Ketones.

J. Org. Chem. 62(23) , 8201-8204, (1997)

A new general route to conjugated enynyl ketones was developed based on a two-step procedure. First, palladium-catalyzed cross-coupling reactions of 1-(benzotriazol-1-yl)propargyl ethyl ether (3) and ...

Ligand effects on Negishi couplings of alkenyl halides.

Org. Lett. 13(15) , 3818-21, (2011)

Negishi couplings at olefinic centers do not always occur with the anticipated maintenance of stereochemistry. The source of erosion has been traced to the ligand, and a modified method has been devel...

Spiro [2.4] hepta-1, 4, 6-triene Billups WE, et al.

J. Am. Chem. Soc. 116(14) , 6463, (1994)

 Synonyms

β-(trimethylsilyl)vinyl bromide
MFCD00040824
[(E)-2-BROMOVINYL](TRIMETHYL)SILANE
2-BROMOVINYLTRIMETHYLSILANE
2-(BROMOVINYL)TRIMETHYLSILANE
(2-BROMOVINYL)TRIMETHYLSILANE