Shanghai Jizhi Biochemical Technology Co., Ltd
China
Product Name: (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
Price: ￥638.0/250mg ￥1918.0/1g
Purity: 99.0%
Stocking Period: Inquiry
Contact: Liu jia

Dayang Chem (Hangzhou) Co., Ltd.
China
Product Name: Acetylacetonato(1,5-cyclooctadiene)rhodium(I)
Price: $Inquiry/100g $Inquiry/1kg $Inquiry/100kg $Inquiry/1000kg
Purity: 98.0%
Stocking Period: Inquiry
Contact: Ms Wang

12245-39-5

12245-39-5 structure

Name: (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
Chemical Name: acetylacetonato(1,5-cyclooctadiene)rhodium(i)
CAS Number: 12245-39-5
Molecular Formula: C₁₃H₁₉O₂Rh
Molecular Weight: 310.194
Catalog: Organic raw materials Organometallic compound Organic
Create Date: 2018-11-28 21:09:54
Modify Date: 2024-01-14 16:20:20

Name	acetylacetonato(1,5-cyclooctadiene)rhodium(i)
Synonyms	(1,5-cyclooctadiene)(2,4-pentanedionato)-rhodiu (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I) (1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate acetylacetonate-1,5-cyclooctadienerhodium MFCD00075046 Rh(acac)(COD) [4-(Hydroxy-κO)-3-penten-2-onato]rhodium - (1Z,5Z)-1,5-cyclooctadiene (1:1) Acetylacetonato(1,5 RHODIUM (1,5-CYCLOOCTADIENE)-2,4-PENTANEDIONATE (1,5-cyclooctadiene)(2,4-pentanedionato)rhodium Rhodium, [4-(hydroxy-κO)-3-penten-2-onato]-, compd. with (1Z,5Z)-1,5-cyclooctadiene (1:1)

Boiling Point	153.5ºC at 760mmHg
Melting Point	138-140ºC(lit.)
Molecular Formula	C₁₃H₁₉O₂Rh
Molecular Weight	310.194
Flash Point	31.7ºC
Exact Mass	310.044006
PSA	26.30000
LogP	3.63290
Vapour Pressure	4.25mmHg at 25°C
Storage condition	below 5° C

CHEMICAL IDENTIFICATION

RTECS NUMBER :: VI9292000

CHEMICAL NAME :: Rhodium, (1,5-cyclooctadiene)(2,4-pentanedionato)-

CAS REGISTRY NUMBER :: 12245-39-5

LAST UPDATED :: 199712

DATA ITEMS CITED :: 24

MOLECULAR FORMULA :: C13-H19-O2-Rh

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 34 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 45,1,1983 *** REVIEWS *** ACGIH TLV-TWA 1 mg(Rh)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 mg(Rh)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,222,1971 OSHA PEL (Gen Indu):8H TWA 0.1 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 1 mg(Rh)/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg(Rh)/m3 JAN 1993 OEL-DENMARK:TWA 0.001 mg(Rh)/m3 JAN 1993 OEL-DENMARK:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-FINLAND:TWA 0.001 mg(Rh)/m3;Skin JAN 1993 OEL-FINLAND:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-FRANCE:TWA 1 mg(Rh)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.001 mg(Rh)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.001 mg(Rh)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.001 mg(Rh)/m3;STEL 0.003 mg(Rh)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg(Rh)/m3;STEL 0.3 mg(Rh)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

Symbol	GHS07
Signal Word	Warning
Hazard Statements	H315-H319-H335
Precautionary Statements	P261-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes	Xi: Irritant;
Risk Phrases	R36/37/38
Safety Phrases	26-37/39
RIDADR	NONH for all modes of transport
WGK Germany	3
RTECS	VI9292000

12245-39-5	35138-22-8
130296-28-5	82660-97-7
99326-34-8	46360-78-5
849950-56-7	1038932-67-0
540492-55-5	868851-50-7