4837-01-8

4837-01-8 structure
4837-01-8 structure
  • Name: 2-bromoethyl phenyl sulfide
  • Chemical Name: 2-bromoethyl phenyl sulfide
  • CAS Number: 4837-01-8
  • Molecular Formula: C8H9BrS
  • Molecular Weight: 217.12600
  • Create Date: 2018-05-27 08:00:00
  • Modify Date: 2024-01-04 07:33:20

Name 2-bromoethyl phenyl sulfide
Synonyms 2-bromoethylsulfanylbenzene
EINECS 225-422-4
MFCD00040826
2-Bromoethyl Phenyl Sulfide
Density 1.44g/cm3
Boiling Point 261.7ºC at 760mmHg
Molecular Formula C8H9BrS
Molecular Weight 217.12600
Flash Point 112.1ºC
Exact Mass 215.96100
PSA 25.30000
LogP 3.17360
Index of Refraction 1.604

Section I.Chemical Product and Company Identification
Chemical Name 2-Bromoethyl Phenyl Sulfide
Portland OR
Synonym[(2-Bromoethyl)thio]-benzene
Chemical FormulaC6H5SCH2Br
CAS Number4837-01-8

Section II.Composition and Information on Ingredients
Chemical NameCAS Number Percent (%)TLV/PELToxicology Data
2-Bromoethyl Phenyl Sulfide4837-01-8---------- Not available.Not available.

Section III. Hazards Identification
Acute Health EffectsNo specific information is available in our data base regarding the toxic effects of this material for humans. However,
exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if
inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling
this compound. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this
compound.
Chronic Health EffectsCARCINOGENIC EFFECTS : Not available.
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.

Section IV.First Aid Measures
Eye ContactCheck for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention.
Skin ContactIn case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing
before reuse. Thoroughly clean shoes before reuse. Get medical attention.
InhalationIf the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not
improve.
IngestionINDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat.
Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the
toxic material was ingested; the absence of such signs, however, is not conclusive. SEEK IMMEDIATE MEDICAL
ATTENTION in case of ingestion of a radioactive material.

Section V.Fire and Explosion Data
Not available.
FlammabilityMay be combustible at high temperature.Auto-Ignition
Flammable Limits
Flash PointsNot available.
Not available.
Combustion ProductsThese products are toxic carbon oxides (CO, CO 2), sulfur oxides (SO2, SO3...), halogenated compounds.
Fire Hazards
Not available.
Explosion HazardsRisks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media
SMALL FIRE: Use DRY chemical powder.
and InstructionsLARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
Consult with local fire authorities before attempting large scale fire-fighting operations.
Continued on Next Page
2-Bromoethyl Phenyl Sulfide

Section VI.Accidental Release Measures
Spill CleanupAbsorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning the spill by
Instructionsrinsing any contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for
assistance on disposal.

Section VII. Handling and Storage
Handling and StorageKeep away from heat. Mechanical exhaust required. When not in use, tightly seal the container and store in a dry, cool
place. Avoid excessive heat and light. Do not breathe gas/fumes/ vapor/spray.
Information
Always store away from incompatible compounds such as oxidizing agents.

Section VIII. Exposure Controls/Personal Protection
Engineering ControlsProvide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location.
Personal ProtectionSplash goggles. Lab coat. Vapor respirator. Boots. Gloves. Suggested protective clothing might not be sufficient;
consult a specialist BEFORE handling this product. Be sure to use a MSHA/NIOSH approved respirator or equivalent.
Exposure Limits
Not available.

Section IX. Physical and Chemical Properties
Physical state @ 20°CLiquid.Solubility
Not available.
Not available.
Specific Gravity
Molecular WeightPartition Coefficient
217.13Not available.
Boiling PointVapor Pressure
Not available.Not available.
Melting PointNot available.Vapor DensityNot available.
Refractive IndexNot available.VolatilityNot available.
Critical TemperatureNot available.OdorNot available.
ViscosityNot available.TasteNot available.

Section X.Stability and Reactivity Data
Stability
This material is stable if stored under proper conditions. (See Section VII for instructions)
Conditions of InstabilityAvoid excessive heat and light.
Incompatibilities
Reactive with oxidizing agents.

Section XI. Toxicological Information
RTECS NumberNot available.
Routes of ExposureEye Contact. Ingestion. inhalation.
Toxicity DataNot available.
CARCINOGENIC EFFECTS : Not available.
Chronic Toxic Effects
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.
Acute Toxic EffectsNo specific information is available in our data base regarding the toxic effects of this material for humans. However,
exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if
inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling
this compound. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this
compound.
Continued on Next Page
2-Bromoethyl Phenyl Sulfide

Section XII.Ecological Information
EcotoxicityNot available.
Environmental FateNot available.

Section XIII. Disposal Considerations
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissove or mix material with a
Waste Disposal
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
federal, state and locl regulations when disposing of the substance.

Section XIV. Transport Information
DOT ClassificationNot a DOT controlled material (United States).
PIN NumberNot applicable.
Proper Shipping Name
Not applicable.
Packing Group (PG)Not applicable.
DOT Pictograms

Section XV. Other Regulatory Information and Pictograms
TSCA Chemical InventoryThis product is NOT on the EPA Toxic Substances Control Act (TSCA) inventory. The following notices are required by 40
CFR 720.36 (C) for those products not on the inventory list:
(EPA)
(i) These products are supplied solely for use in research and development by or under the supervision of a technically
qualified individual as defined in 40 CFR 720.0 et sec.
(ii) The health risks of these products have not been fully determined. Any information that is or becomes available will be
supplied on an MSDS sheet.
WHMIS ClassificationNot available.
(Canada)
EINECS Number (EEC) 225-422-4
EEC Risk StatementsNot available.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Risk Phrases R36/38
Safety Phrases S26-S36
HS Code 2930909090

~10%

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4837-01-8

Literature: Zheng, Can-Hui; Yang, Hui; Zhang, Meng; Lu, Shi-Hai; Shi, Duo; Wang, Juan; Chen, Xiu-Hua; Ren, Xiao-Hui; Liu, Jia; Lv, Jia-Guo; Zhu, Ju; Zhou, You-Jun Bioorganic and Medicinal Chemistry Letters, 2012 , vol. 22, # 1 p. 39 - 44

~69%

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Literature: Su, Tao; Xie, Shishun; Wei, Hui; Yan, Jun; Huang, Ling; Li, Xingshu Bioorganic and Medicinal Chemistry, 2013 , vol. 21, # 18 p. 5830 - 5840

~93%

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Literature: Moriya, Toshimitsu; Yoneda, Shinichiro; Kawana, Keita; Ikeda, Reiko; Konakahara, Takeo; Sakai, Norio Organic Letters, 2012 , vol. 14, # 18 p. 4842 - 4845,4

~61%

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Literature: Converse, Antonella; Saaidi, Pierre-Loic; Sharpless, K. Barry; Finn Journal of Organic Chemistry, 2004 , vol. 69, # 21 p. 7336 - 7339

~71%

4837-01-8 structure

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Literature: Bucher, Christoph B.; Heimgartner, Heinz Helvetica Chimica Acta, 1996 , vol. 79, # 7 p. 1903 - 1915

~68%

4837-01-8 structure

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Literature: Converse, Antonella; Saaidi, Pierre-Loic; Sharpless, K. Barry; Finn Journal of Organic Chemistry, 2004 , vol. 69, # 21 p. 7336 - 7339

~%

4837-01-8 structure

4837-01-8

Literature: Kochi,J.K. et al. Tetrahedron, 1968 , vol. 24, p. 3503 - 3515

~%

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4837-01-8

Literature: Bayer and Co. Patent: DE406151 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 14, p. 1284
HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%