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Related CAS#:
101-38-2 439106-87-3
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101-38-2

101-38-2 structure
101-38-2 structure
  • Name: 2,6-Dichloroquinone-4-chloroimide
  • Chemical Name: 2,6-Dichloroquinone-4-chloroimide
  • CAS Number: 101-38-2
  • Molecular Formula: C6H2Cl3NO
  • Molecular Weight: 210.445
  • Catalog: Chemical reagent Organic reagent Imide
  • Create Date: 2018-09-25 10:26:09
  • Modify Date: 2024-01-02 19:05:19
  • 2,6-Dichloroquinone-4-chloroimide is a spray reagent for organic compounds. 2,6-Dichloroquinone-4-chloroimide can be used in thin-layer chromatograms. 2,6-Dichloroquinone-4-chloroimide can be used as an optical sensor for rapid detection of permethrin in treated wood[1][2].
Name 2,6-Dichloroquinone-4-chloroimide
Synonyms 2,6-dichloro-4-(chloroimino)cyclohexa-2,5-dien-1-one
2,6-Dichloro-p-benzoquinone-4-chloroimine
N,2,6-Trichloro-p-quinoneimine
2,6-dichloro-4-chloroiminocyclohexa-2,5-dien-1-one
2,5-Cyclohexadien-1-one, 2,6-dichloro-4-(chloroimino)-
n,2,6-trichloroquinoneimine
N,2,6-Trichloro-p-benzoquinone Monoimine
2,6-Dichloro-4-(chloroimino)-2,5-cyclohexadien-1-one
2,6-Dichloroquinone-4-chloroiMide
MFCD00001611
2,6-Dichloro-4-(chloroimino)cyclohexa-2,5-dienone
EINECS 202-937-2
Description 2,6-Dichloroquinone-4-chloroimide is a spray reagent for organic compounds. 2,6-Dichloroquinone-4-chloroimide can be used in thin-layer chromatograms. 2,6-Dichloroquinone-4-chloroimide can be used as an optical sensor for rapid detection of permethrin in treated wood[1][2].
Related Catalog
References

[1]. Joseph H. Ross, et al. 2,6-Dichloroquinone 4-chloroimide as a reagent for amines and aromatic hydrocarbons on thin-layer chromatograms. Anal. Chem. 1968, 40, 14, 2138–2143.

[2]. Arip MN, et al. Reaction of 2,6-dichloroquinone-4-chloroimide (Gibbs reagent) with permethrin - an optical sensor for rapid detection of permethrin in treated wood. Chem Cent J. 2013 Jul 16;7:122.
Density 1.6±0.1 g/cm3
Boiling Point 262.3±50.0 °C at 760 mmHg
Melting Point 65-67 °C(lit.)
Molecular Formula C6H2Cl3NO
Molecular Weight 210.445
Flash Point 104.3±19.3 °C
Exact Mass 208.920197
PSA 29.43000
LogP 1.64
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.612
Stability Stable. Keep refrigerated.

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GU5470000
CHEMICAL NAME :
2,5-Cyclohexadien-1-one, 4-chloroimino-2,6-dichloro-
CAS REGISTRY NUMBER :
101-38-2
BEILSTEIN REFERENCE NO. :
2364249
LAST UPDATED :
199701
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C6-H2-Cl3-N-O
MOLECULAR WEIGHT :
210.44
WISWESSER LINE NOTATION :
L6V DYJ BG DUNG FG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,21,1953
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
20 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 21,11,1978
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00254 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 82266 No. of Facilities: 56 (estimated) No. of Industries: 2 No. of Occupations: 5 No. of Employees: 1120 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 82266 No. of Facilities: 25 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1358 (estimated) No. of Female Employees: 956 (estimated)
Hazard Codes E:Explosive;Xn:Harmful;
Risk Phrases R2;R20/22;R36/37/38
Safety Phrases S15-S26-S36/37/39-S33-S16
RIDADR UN 3224 4.1
WGK Germany 3
RTECS GU5470000
5930-28-9 structure

5930-28-9

~%

101-38-2 structure

101-38-2
Literature: Journal of Biological Chemistry, , vol. 72, p. 659 Journal of Physical Chemistry, , vol. 31, p. 1057
88-06-2 structure

88-06-2

~34%

101-38-2 structure

101-38-2

697-91-6 structure

697-91-6
Literature: Environmental Science and Technology, , vol. 38, # 19 p. 5022 - 5029
88-06-2 structure

88-06-2

~32%

101-38-2 structure

101-38-2

20244-55-7 structure

20244-55-7
697-91-6 structure

697-91-6
Literature: Environmental Science and Technology, , vol. 38, # 19 p. 5022 - 5029
618-80-4 structure

618-80-4

~%

101-38-2 structure

101-38-2
Literature: Trudy Inst. c. chim. Reakt., , # 16 p. 83,85 Chem. Zentralbl., , vol. 113, # II p. 397 Rev. quim. farm. Chile, , # 47 p. 7,10 Science Reports of National Tsing Hua University, Series A: Mathematical, Physical, and Engineering Sciences, , vol. 2, p. 235,238
7647-01-0 structure

7647-01-0
5930-28-9 structure

5930-28-9

~%

101-38-2 structure

101-38-2
Literature: Justus Liebigs Annalen der Chemie, , vol. 234, p. 3

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