Name | 5-Methyl-3-nitropyridin-2-amine |
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Synonyms |
2-Amino-3-nitro-5-picoline
5-Methyl-3-nitropyridin-2-amin 5-Methyl-3-nitro-2-pyridinamine 5-Methyl-3-nitropyridin-2-amine 2-Pyrazinecarboxylic acid, 3-amino-, methyl ester 2-Pyridinamine, 5-methyl-3-nitro- methyl 3-aminopyrazine-2-carboxylate Methyl 3-amino-2-pyrazinecarboxylate MFCD00047442 |
Density | 1.4±0.1 g/cm3 |
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Boiling Point | 318.9±37.0 °C at 760 mmHg |
Melting Point | 189-193 °C |
Molecular Formula | C6H7N3O2 |
Molecular Weight | 153.139 |
Flash Point | 146.7±26.5 °C |
Exact Mass | 153.053833 |
PSA | 84.73000 |
LogP | 2.08 |
Vapour Pressure | 0.0±0.7 mmHg at 25°C |
Index of Refraction | 1.625 |
Synonym:2-Amino-5-methyl-3-nitropyridine Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 7598-26-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: off-white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C6H7N3O2 Molecular Weight: 153.14 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, excess heat, exposure to flame. Incompatibilities with Other Materials: Strong oxidizing agents, acids, acid chlorides, acid anhydrides. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 7598-26-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 6-Amino-5-nitro-3-picoline - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 22 Do not breathe dust. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 7598-26-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 7598-26-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 7598-26-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xn: Harmful; |
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Risk Phrases | R36/37/38 |
Safety Phrases | S36/37/39-S26-S22 |
HS Code | 2933399090 |
~26% 7598-26-7 |
Literature: CHEMOCENTRYX, INC. Patent: WO2006/76644 A2, 2006 ; Location in patent: Page/Page column 204 ; WO 2006/076644 A2 |
~41% 7598-26-7 |
Literature: Troschutz; Luckel Archiv der Pharmazie, 1992 , vol. 325, # 12 p. 785 - 789 |
~28% 7598-26-7 |
Literature: Sepiol, Jadwiga; Tomasik, Piotr Acta Chimica Hungarica, 1986 , vol. 121, # 4 p. 333 - 338 |
Precursor 4 | |
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DownStream 4 | |
HS Code | 2933399090 |
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Summary | 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |