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14323-32-1

14323-32-1 structure
14323-32-1 structure
  • Name: Potassium tetrabromoaurate(III)
  • Chemical Name: potassium tetrabromoaurate
  • CAS Number: 14323-32-1
  • Molecular Formula: AuBr4K
  • Molecular Weight: 555.68100
  • Create Date: 2018-07-12 22:11:13
  • Modify Date: 2024-04-05 19:09:17

Name potassium tetrabromoaurate
Synonyms potassium,gold(3+),tetrabromide
EINECS 238-268-8
MFCD00049650
Potassium Tetrabromoaurate(Iii) Dihydrate
Boiling Point 25°C
Melting Point -132°C
Molecular Formula AuBr4K
Molecular Weight 555.68100
Exact Mass 551.60400
LogP 3.37990

Section 1: Product Identification
Chemical Name:Potassium tetrabromoaurate (III) dihydrate, 99%
CAS Registry Number:14323-32-1
Formula:KAuBr4.2H2O
EINECS Number:238-268-8
Chemical Family:halometallate salt
Synonym:Potassium gold tetrabromide hydrate

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound14323-32-1100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust.
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion may lead to dermatitis, dizziness, metallic taste, abdominal cramps, vomiting, bloody diarrhea,
Ingestion:
weakness, and convulsions.
Irritating to skin, eyes and respiratory tract. Gold compounds may cause impairment of kidney and bone
Acute Health Affects:
marrow function, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Prolonged exposure to gold compounds may lead to reduced red and white blood cell generation. Prolonged
Chronic Health Affects:
exposure to bromides may cause skin rashes, memory loss, irritability, and headache.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:None. Material is non-flammable.
Special Fire Fighting Procedures:No special fire fighting procedures required.
Hazardous Combustion andnone
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable
Spill and Leak Procedures:
inert material and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store solid in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:reddish-brown xtl.
Molecular Weight:555.71 (591.74)
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:very soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:Active metals
Decomposition Products:potassium bromide, gold, bromine, hydrobromic acid and water.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Risk Phrases 34
Safety Phrases S36/37
WGK Germany 3

~%

14323-32-1 structure

14323-32-1

Literature: Gmelin Handbook: Au: MVol.3, 6.3, page 618 - 621

~%

14323-32-1 structure

14323-32-1

Literature: Booth; Bhargava; Bond; O'Mullane Journal of Physical Chemistry B, 2006 , vol. 110, # 25 p. 12419 - 12426
Precursor  2

DownStream  1