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28165-50-6

28165-50-6 structure
28165-50-6 structure

Name 2-Amino-6-bromophenol
Synonyms ZR BQ CE
2-amino-6-bromo-phenol
Phenol, 2-amino-6-bromo-
MFCD08277300
6-bromo-2-amino Phenol
6-amino-2-bromophenol
2-bromo-6-amino phenol
Phenol,2-amino-6-bromo
2-Amino-6-bromophenol
3-BROMO-2-HYDROXYANILINE
Density 1.8±0.1 g/cm3
Boiling Point 246.4±25.0 °C at 760 mmHg
Melting Point 83-84ºC
Molecular Formula C6H6BrNO
Molecular Weight 188.022
Flash Point 102.8±23.2 °C
Exact Mass 186.963272
PSA 46.25000
LogP 1.82
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.677
Storage condition 2-8°C
Material Safety Data Sheet

Section1. Identification of the substance
Product Name: 2-Amino-6-bromophenol
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
H302:Harmful if swallowed
H410:Very toxic to aquatic life with long lasting effects
P273:Avoid release to the environment

Section3. Composition/information on ingredients.
Ingredient name:2-Amino-6-bromophenol
CAS number:28165-50-6

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Storage:Store in closed vessels.

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
Melting point:No data
Flash point:No data
Density:No data
Molecular formula: C6H6BrNO
Molecular weight: 188

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, hydrogen bromide.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
Non-harzardous for air and ground transportation.

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi
Risk Phrases 22-50/53
Safety Phrases 60-61
HS Code 2922299090

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28165-50-6 structure

28165-50-6

Literature: Costales, Abran; Mathur, Michelle; Ramurthy, Savithri; Lan, Jiong; Subramanian, Sharadha; Jain, Rama; Atallah, Gordana; Setti, Lina; Lindvall, Mika; Appleton, Brent A.; Ornelas, Elizabeth; Feucht, Paul; Warne, Bob; Doyle, Laura; Basham, Stephen E.; Aronchik, Ida; Jefferson, Anne B.; Shafer, Cynthia M. Bioorganic and Medicinal Chemistry Letters, 2014 , vol. 24, # 6 p. 1592 - 1596

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28165-50-6 structure

28165-50-6

Literature: Zhao, Shu-Hai; Berger, Jacob; Clark, Robin D.; Sethofer, Steven G.; Krauss, Nancy E.; Brothers, Julie M.; Martin, Renee S.; Misner, Dinah L.; Schwab, Dietmar; Alexandrova, Ludmila Bioorganic and Medicinal Chemistry Letters, 2007 , vol. 17, # 12 p. 3504 - 3507

~4%

Detail
Literature: Novak, Michael; Rovin, Lise H.; Pelecanou, Maria; Mulero, Julio J.; Lagerman, Robert K. Journal of Organic Chemistry, 1987 , vol. 52, # 10 p. 2002 - 2010

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Detail
Literature: Novak, Michael; Lagerman, Robert K. Journal of Organic Chemistry, 1988 , vol. 53, # 20 p. 4762 - 4769
HS Code 2922299090
Summary 2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%