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111-60-4

111-60-4 structure
111-60-4 structure

Name 2-Hydroxyethyl stearate
Synonyms EINECS 203-886-9
ethylene glycol monostearate
MFCD00051465
Density 0.913 g/cm3
Boiling Point 149 °C
Melting Point 55-60 °C
Molecular Formula C20H40O3
Molecular Weight 328.53000
Flash Point 240ºC
Exact Mass 328.29800
PSA 46.53000
LogP 5.78340
Name: 2-Hydroxyethyl stearate 95% Material Safety Data Sheet
Synonym: Ethylene Glycol Stearate; Glycol Stearate
CAS: 111-60-4
Section 1 - Chemical Product MSDS Name:2-Hydroxyethyl stearate 95% Material Safety Data Sheet
Synonym:Ethylene Glycol Stearate; Glycol Stearate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
111-60-4 2-Hydroxyethyl stearate 95% 203-886-9
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 149 deg C
Freezing/Melting Point: 57 - 59 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 328.53

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 111-60-4: WI4100000 LD50/LC50:
CAS# 111-60-4: Draize test, rabbit, skin: 500 mg/24H Mild.
Carcinogenicity:
2-Hydroxyethyl stearate - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 111-60-4: 1
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 111-60-4 is listed on Canada's DSL List.
CAS# 111-60-4 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 111-60-4 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WI4100000
CHEMICAL NAME :
Stearic acid, 2-hydroxyethyl ester
CAS REGISTRY NUMBER :
111-60-4
BEILSTEIN REFERENCE NO. :
1794033
LAST UPDATED :
199706
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C20-H40-O3
MOLECULAR WEIGHT :
328.60
WISWESSER LINE NOTATION :
Q2OV17

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 1(2),1,1982 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 32500 No. of Facilities: 1109 (estimated) No. of Industries: 13 No. of Occupations: 18 No. of Employees: 10112 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 32500 No. of Facilities: 5980 (estimated) No. of Industries: 42 No. of Occupations: 68 No. of Employees: 218214 (estimated) No. of Female Employees: 167909 (estimated)
Hazard Codes T
Risk Phrases R60
Safety Phrases S24/25-S45-S36/37/39-S28-S27-S26-S53
RTECS WI4100000
HS Code 2915709000

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Literature: Iwashita, Masazumi; Makide, Kumiko; Nonomura, Taro; Misumi, Yoshimasa; Otani, Yuko; Ishida, Mayuko; Taguchi, Ryo; Tsujimoto, Masafumi; Aoki, Junken; Arai, Hiroyuki; Ohwada, Tomohiko Journal of Medicinal Chemistry, 2009 , vol. 52, # 19 p. 5837 - 5863

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Literature: THE MALAGHAN INSTITUTE OF MEDICAL RESEARCH; UNIVERSITY OF OTAGO; AGRESEARCH LIMITED Patent: WO2005/49631 A1, 2005 ; Location in patent: Page/Page column 61 ;

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Literature: Hosseini-Sarvari, Mona; Sodagar, Esmat Comptes Rendus Chimie, 2013 , vol. 16, # 3 p. 229 - 238

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Literature: Sharghi, Hashem; Sarvari, Mona Hosseini Tetrahedron, 2003 , vol. 59, # 20 p. 3627 - 3633

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Literature: Journal of the Chemical Society, , p. 1918

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Literature: Journal of the Chemical Society, , p. 1043

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Literature: Journal of the Chemical Society, , p. 1043

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Literature: Bulletin de la Societe Chimique de France, , p. 927 US1733639 , ;
HS Code 2915709000
Summary 2915709000. palmitic acid and its salts and esters. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%