Alpha-pinene
Names
[ CAS No. ]:
80-56-8
[ Name ]:
Alpha-pinene
[Synonym ]:
α-PINENE, (+)-
EINECS 201-291-9
Pina-2-ene
PC500
L46 A EUTJ A1 A1 D1 &&(+)-α or (1R,5R)- Form
AciteneA
(1R)-(+)-α-Pinene
1R-(+)-α-pinene
PERMOUNT
(1R,5R)-2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene
MFCD00212495
Australene
Bicyclo(3.1.1)hept-2-ene, 2,6,6-trimethyl-, (1R,5R)-
α-Pinene
2-Pinene
Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl-, (1R,5R)-
(1R,5R)-α-pinene
pin-2-ene
(1R,5R)-2-Pinene
Alpha-Pinene
Pinene
c 500
Chemical & Physical Properties
[ Density]:
0.858
[ Boiling Point ]:
154-157 ºC
[ Melting Point ]:
-55°C
[ Molecular Formula ]:
C10H16
[ Molecular Weight ]:
136.234
[ Flash Point ]:
38 ºC
[ Exact Mass ]:
136.125198
[ LogP ]:
4.37
[ Vapour Pressure ]:
3.5±0.1 mmHg at 25°C
[ Index of Refraction ]:
1.465-1.467
[ Stability ]:
Stable. Flammable. Incompatible with strong oxidizing agents.
[ Water Solubility ]:
insoluble
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- DT7000000
- CHEMICAL NAME :
- Bicyclo(3.1.1)hept-2-ene, 2,6,6-trimethyl-
- CAS REGISTRY NUMBER :
- 80-56-8
- BEILSTEIN REFERENCE NO. :
- 3194807
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 12
- MOLECULAR FORMULA :
- C10-H16
- MOLECULAR WEIGHT :
- 136.26
- WISWESSER LINE NOTATION :
- L46 A EUTJ A1 A1 E1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Human - man
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,853,1978
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,853,1978 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 3700 mg/kg
- TOXIC EFFECTS :
- Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - other changes
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,853,1978
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 625 ug/m3
- TOXIC EFFECTS :
- Brain and Coverings - recordings from specific areas of CNS Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,853,1978
- TYPE OF TEST :
- LD - Lethal dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- >500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 4,232,1952
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 572 ug/m3
- TOXIC EFFECTS :
- Brain and Coverings - recordings from specific areas of CNS Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,853,1978 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M4022 No. of Facilities: 214 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 815 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M4022 No. of Facilities: 7593 (estimated) No. of Industries: 92 No. of Occupations: 72 No. of Employees: 153143 (estimated) No. of Female Employees: 47130 (estimated)
Safety Information
[ Symbol ]:
GHS02, GHS07, GHS08
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H226-H304-H315-H317
[ Precautionary Statements ]:
P280-P301 + P310-P331
[ Hazard Codes ]:
Xn:Harmful;
[ Risk Phrases ]:
R10;R36/37/38;R51/53;R65
[ Safety Phrases ]:
S26-S36/37-S61-S37/39-S29-S16
[ RIDADR ]:
UN 2368 3/PG 3
[ WGK Germany ]:
1
[ RTECS ]:
DT7000000
[ Packaging Group ]:
III
[ Hazard Class ]:
3.2
[ HS Code ]:
2902191000
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2902191000
[ Summary ]:
2902191000 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。Lowest tariff:2.0%。General tariff:30.0%
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