1,1,1,2-tetrachloro-2,2-difluoroethane
Names
[ CAS No. ]:
76-11-9
[ Name ]:
1,1,1,2-tetrachloro-2,2-difluoroethane
[Synonym ]:
1-chloro-1,1-difluoro-2,2,2-trichloro-ethane
f112a
tetrachlorodifluoroethane
1,1-difluoro-1,2,2,2-tetrachloroethane
MFCD00000798
Fron-112a
freon112a
tetrachloro-2,2-difluoroethane
2,2-DIFLUORO-5-AMINO-6-CHLORO-1,3-BENZODIOXOLE
cfc112a
Genetron131
EINECS 200-934-0
1,1,1,2-tetrachloro-2,2-difluoroethane
1,1-difluoro-tetrachloroethane
Freon BU
difluorotetrachloroethane
refrigerant112a
r112a
halocarbon112a
Chemical & Physical Properties
[ Density]:
1.726 g/cm3
[ Boiling Point ]:
93.3ºC at 760 mmHg
[ Melting Point ]:
39-44ºC
[ Molecular Formula ]:
C2Cl4F2
[ Molecular Weight ]:
203.83000
[ Flash Point ]:
11.8ºC
[ Exact Mass ]:
201.87200
[ LogP ]:
3.18820
[ Index of Refraction ]:
1.4046
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- KI1425000
- CHEMICAL NAME :
- Ethane, 2,2-difluoro-1,1,1,2-tetrachloro-
- CAS REGISTRY NUMBER :
- 76-11-9
- BEILSTEIN REFERENCE NO. :
- 1699461
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 26
- MOLECULAR FORMULA :
- C2-Cl4-F2
- MOLECULAR WEIGHT :
- 203.82
- WISWESSER LINE NOTATION :
- GXGGXGFF
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >8 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NATUAS Nature. (Nature Subscription Dept., POB 1018, Manasguan, NJ 08736) V.1- 1869- Volume(issue)/page/year: 210,744,1966
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 20000 ppm/30M
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 19,1,1971 *** REVIEWS *** ACGIH TLV-TWA 4170 mg/m3 (500 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 500 ppm (4170 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,249,1971 OSHA PEL (Gen Indu):8H TWA 500 ppm (4170 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 500 ppm (4170 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 500 ppm (4170 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 500 ppm (4170 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 500 ppm (4170 mg/m3) JAN 1993 OEL-BELGIUM:TWA 500 ppm (4170 mg/m3) JAN 1993 OEL-DENMARK:TWA 500 ppm (4170 mg/m3) JAN 1993 OEL-FINLAND:TWA 500 ppm (4170 mg/m3);STEL 625 ppm (5215 mg/m3) JAN 1993 OEL-FRANCE:TWA 500 ppm (4170 mg/m3) JAN 1993 OEL-GERMANY:TWA 1000 ppm (8340 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 500 ppm (4170 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 500 ppm (4170 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 500 ppm (4200 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 100 ppm (834 mg/m3);STEL 100 ppm JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO 1,1,1,2-TETRACHLORO-2,2-DIFLUOROETHANE-air:TWA 500 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992
Safety Information
[ Hazard Codes ]:
N: Dangerous for the environment;Xi: Irritant;
[ Risk Phrases ]:
R59;R36/37/38
[ Safety Phrases ]:
S59-S37/39-S26