Diphenylphosphine oxide
Names
[ CAS No. ]:
4559-70-0
[ Name ]:
Diphenylphosphine oxide
[Synonym ]:
oxo(diphenyl)phosphanium
Diphenylphosphine oxide
Phosphorane, diphenyl-, oxide
MFCD00002079
Chemical & Physical Properties
[ Boiling Point ]:
329.2±25.0 °C at 760 mmHg
[ Melting Point ]:
56-57 °C(lit.)
[ Molecular Formula ]:
C12H11OP
[ Molecular Weight ]:
202.189
[ Flash Point ]:
152.9±23.2 °C
[ Exact Mass ]:
202.054749
[ PSA ]:
40.54000
[ LogP ]:
1.29
[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C
[ Index of Refraction ]:
1.608-1.61
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xn:Harmful;
[ Risk Phrases ]:
R22;R36/37/38
[ Safety Phrases ]:
S26
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
2
[ HS Code ]:
2902909090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2902909090
[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%
Articles
Tetrahedron Lett. 31 , 5571, (1990)
Kurz, L.; Lee, G.; Morgans, D. et al.
Tetrahedron Lett. 31 , 632, (1990)
Alcock, N. W.; Brown, J. M.; Hulmes, D. I.
Tetrahedron Asymmetry 4 , 743, (1993)