(3Z)-3-Hexen-1-yl acetate

Names

[ Name ]:
(3Z)-3-Hexen-1-yl acetate

[Synonym ]:
Leaf Acetate
HEX-3ENYLSALICYLATE
(3Z)-Hex-3-en-1-yl acetate
hexenyl salicylate cis-3
cis-3-Hexenyl acetate
Z-3-hexenyl salicylate
Leaf salicylate
3-hexenylsalicylate
cis-3-hexene-1-ol acetate
Acetic Acid cis-3-Hexenyl Ester
EINECS 222-960-1
MFCD00036563
Cis-Hexenyl Salicylate
cis-3-hexen-1-yl salicylate
C3 HEXENYL SALICYLATE
3-Hexen-1-ol, acetate, (3Z)-
cis-3-hexenyl salkylate
3-Hexen-1-yl salicylate
HEXENYLSALICYLAT CIS-3
(3Z)-3-Hexen-1-ol acetate,(3Z)-C-3-Hexenyl acetate,Leaf acetate
cis-3-Hexen-1-yl acetate
(3Z)-3-Hexen-1-yl acetate
CA14202500 cis-3-Hexenyl

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
174.2±19.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₁₄O₂

[ Molecular Weight ]:
142.196

[ Flash Point ]:
67.5±19.9 °C

[ Exact Mass ]:
142.099380

[ PSA ]:
1.90580

[ LogP ]:
2.41

[ Vapour Pressure ]:
1.2±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.433

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MP8425050

CHEMICAL NAME :: 3-Hexen-1-ol, acetate, (Z)-

CAS REGISTRY NUMBER :: 3681-71-8

BEILSTEIN REFERENCE NO. :: 1721854

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C8-H14-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 13,454,1975

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 13,454,1975 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7452 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 1557 (estimated) No. of Female Employees: 276 (estimated)

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
T+

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 3272 3/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
MP8425050

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2915390090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2915390090

[ Summary ]:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

Articles

Identification of olfactory receptor neurons in Uraba lugens (Lepidoptera: Nolidae) and its implications for host range.

J. Insect Physiol. 78 , 33-46, (2015)

Phytophagous insects detect volatile compounds produced by host and non-host plants, using species-specific sets of olfactory receptor neurons (ORNs). To investigate the relationship between the range...

Isoprene emission by poplar is not important for the feeding behaviour of poplar leaf beetles.

BMC Plant Biol. 15 , 165, (2015)

Chrysomela populi (poplar leaf beetle) is a common herbivore in poplar plantations whose infestation causes major economic losses. Because plant volatiles act as infochemicals, we tested whether isopr...

Mosquito odorant receptor for DEET and methyl jasmonate.

Proc. Natl. Acad. Sci. U. S. A. 111(46) , 16592-7, (2014)

Insect repellents are important prophylactic tools for travelers and populations living in endemic areas of malaria, dengue, encephalitis, and other vector-borne diseases. DEET (N,N-diethyl-3-methylbe...