Methyl phenyl sulfone

Names

[ Name ]:
Methyl phenyl sulfone

[Synonym ]:
Sulfone,methyl phenyl
methyl phenyl
Benzene, (methylsulfonyl)-
methylphenylsulphone
EINECS 221-476-8
MFCD00014741
phenyl methyl sulphone
MeSO2Ph
(Methylsulfonyl)benzene
1-(methylsulfonyl)benzene
Methyl phenyl sulfone
phenyl methyl sulfone
thioanisole sulfone

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
302.6±15.0 °C at 760 mmHg

[ Melting Point ]:
85-87 °C

[ Molecular Formula ]:
C₇H₈O₂S

[ Molecular Weight ]:
156.202

[ Flash Point ]:
171.4±13.1 °C

[ Exact Mass ]:
156.024506

[ PSA ]:
42.52000

[ LogP ]:
0.50

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.525

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: WR6800000

CHEMICAL NAME :: Sulfone, methyl phenyl

CAS REGISTRY NUMBER :: 3112-85-4

BEILSTEIN REFERENCE NO. :: 1906914

LAST UPDATED :: 199710

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C7-H8-O2-S

MOLECULAR WEIGHT :: 156.21

WISWESSER LINE NOTATION :: WS1&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1470 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PCBPBS Pesticide Biochemistry and Physiology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1971- Volume(issue)/page/year: 1,356,1971

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
WR6800000

[ HS Code ]:
2904100000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2904100000

[ Summary ]:
2904100000 derivatives containing only sulpho groups, their salts and ethyl esters。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

M. Julia, D. Deprez

Tetrahedron Lett. , 277, (1976)

P.A. Bartlett et al.

J. Am. Chem. Soc. 100 , 4852, (1978)

M. Julia et al.

J. Chem. Soc. Perkin Trans. I , 1646, (1978)