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methyl phenyl sulfoxide

Names

[ CAS No. ]:
1193-82-4

[ Name ]:
methyl phenyl sulfoxide

[Synonym ]:
methylsulfinylbenzene
Methyl phenyl sulfoxide
EINECS 214-781-2
MFCD00002088

Chemical & Physical Properties

[ Boiling Point ]:
139-140 °C14 mm Hg(lit.)

[ Melting Point ]:
26-29 °C(lit.)

[ Molecular Formula ]:
C7H8OS

[ Molecular Weight ]:
140.20300

[ Flash Point ]:
187 °F

[ Exact Mass ]:
140.03000

[ PSA ]:
36.28000

[ LogP ]:
2.28970

[ Vapour Pressure ]:
0.0109mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.5775(lit.)

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H315-H318-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
37/38-41

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

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BMC Complement Altern. Med. 13 , 7, (2013)

Inhibition of the proteolytic activity of 26S proteasome, the protein-degrading machine, is now considered a novel and promising approach for cancer therapy. Interestingly, proteasome inhibitors have ...

Resolution of racemic sulfoxides with high productivity and enantioselectivity by a Rhodococcus sp. strain as an alternative to biooxidation of prochiral sulfides for efficient production of enantiopure sulfoxides.

Bioresour. Technol. 102(2) , 1537-42, (2011)

Whole cells of Rhodococcus sp. ECU0066 were used a catalyst for resolution of racemic sulfoxides, as an alternative to asymmetric oxidation of sulfides for efficient production of enantiopure sulfoxid...

Biocatalytic oxidation by chloroperoxidase from Caldariomyces fumago in polymersome nanoreactors.

Org. Biomol. Chem. 7 , 4604-4610, (2009)

The encapsulation of chloroperoxidase from Caldariomyces fumago (CPO) in block copolymer polymersomes is reported. Fluorescence and electron microscopy show that when the encapsulating conditions favo...


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