Sodium tert-pentoxide

Names

[ Name ]:
Sodium tert-pentoxide

[Synonym ]:
sodium 2-methylpropan-2-olate
MFCD00064245
sodium tert-butanolate
sodium tertiary-butoxide
sodium t-butanolate
Na-t-pentoxide
sodium tert-amylate
sodium tert-butylate
tBuONa
Sodium-t-amylate
1-Propanol, 2,2-dimethyl-, sodium salt (1:1)
sodium t-butoxide
potassium tert-butylate
sodium-tert-butoxide
Sodium 2,2-dimethyl-1-propanolate
NaOtBu
t-butoxy sodium
NaOt-amylate
Sodium tert-Pentoxide
Na t-amylate
EINECS 238-639-4
Sodium 2-Methyl-2-butoxide
t-pentylONa
Sodium tert-pentyloxide
sodium tert-pentylate

Chemical & Physical Properties

[ Density]:
0.904 g/mL at 25 °C

[ Boiling Point ]:
113.1ºC at 760 mmHg

[ Melting Point ]:
200°C

[ Molecular Formula ]:
C₅H₁₁NaO

[ Molecular Weight ]:
110.130

[ Flash Point ]:
-21 °C

[ Exact Mass ]:
110.070763

[ PSA ]:
23.06000

[ LogP ]:
1.60550

[ Vapour Pressure ]:
19.2mmHg at 25°C

[ Storage condition ]:
Flammables + water-Freezer (-20°C)e area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H251-H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P235 + P410-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
F:Flammable;C:Corrosive;

[ Risk Phrases ]:
R11;R14;R35

[ Safety Phrases ]:
S6-S22-S33-S36/37/39-S7/8-S45-S43C-S26-S16

[ RIDADR ]:
UN 3206 4.2/PG 2

[ WGK Germany ]:
1

[ Packaging Group ]:
II

[ Hazard Class ]:
4.1

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Heterolysis of Dihydrogen by Silver Alkoxides and Fluorides.

Chemistry 21 , 10160-9, (2015)

Alkoxide-bridged disilver cations react with dihydrogen to form hydride-bridged cations, releasing free alcohol. Hydrogenolysis of neutral silver fluorides affords hydride-bridged disilver cations as ...