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Aluminum acetylacetonate

Names

[ CAS No. ]:
13963-57-0

[ Name ]:
Aluminum acetylacetonate

[Synonym ]:
ACETYLACETONE ALUMINIUM
Alumium acety acetonate
3-Penten-2-one, 4-hydroxy-, aluminum salt (3:1)
tris-pentane-2,4-dionato aluminium
Aluminum acetoacetonate
aluminium tris(acetylacetonate)
aluminum acetyl acetonate
Aluminum(III) acetylacetonate
Aluminium tris(4-oxo-2-penten-2-olate)
Acetylacetone Aluminum(III) Salt
Aluminum Chelate A
Dotite Al
Alumin
Aluminum Acetylacetonate
EINECS 237-741-6
Al(acac)3,Aluminum 2,4-pentanedionate
Aluminium acetylacetonate
AL(ACAC)3
Aluminum triacetylacetone
aluminum(III) trisacetylacetonate
Nacem Aluminum
Aluminum 2,4-pentanedionate
MFCD00000013
Tris(2,4-pentanedionato)aluminum(III)
ALUMINUM(III) AA

Chemical & Physical Properties

[ Density]:
1,27 g/cm3

[ Boiling Point ]:
315 °C(lit.)

[ Melting Point ]:
190-193 °C(lit.)

[ Molecular Formula ]:
C15H21AlO6

[ Molecular Weight ]:
324.305

[ Flash Point ]:
314-316°C

[ Exact Mass ]:
324.115356

[ PSA ]:
78.90000

[ LogP ]:
2.88030

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
2.5 G/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BD2230000
CHEMICAL NAME :
Aluminum, tris(2,4-pentanedionato)-
CAS REGISTRY NUMBER :
13963-57-0
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C15-H21-Al-O6
MOLECULAR WEIGHT :
324.34
WISWESSER LINE NOTATION :
D6O-AL-O BDJ D1 F1 B-& BD6O-AL-O BDJ D1 F1 B-& BD6O-AL-O BDJ D1 F1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
178 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02376 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
3600 ug/kg/9D-I
TOXIC EFFECTS :
Cardiac - cardiomyopathy including infarction Cardiac - other changes Related to Chronic Data - death
REFERENCE :
TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 39,185,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6003 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 28 (estimated)

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300-H315-H317-H319-H335

[ Precautionary Statements ]:
P261-P264-P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R25;R36

[ Safety Phrases ]:
26-36/37/39-45-28A

[ RIDADR ]:
UN 3467 6.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
BD2230000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2914190090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2914190090

[ Summary ]:
2914190090 other acyclic ketones without other oxygen function。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Does aluminum lactate cause spinal cord infarction in rabbits?

Environ. Health Perspect. 96 , 245, (1991)

Low-temperature synthesis of gamma-alumina nanocrystals from aluminum acetylacetonate in nonaqueous media.

Small 3(5) , 763-7, (2007)

Procedures for labeling the high-resolution axis of two-dimensional MQ-MAS NMR spectra of half-integer quadrupole spins.

Solid State Nucl. Magn. Reson. 21(1-2) , 21-43, (2002)

The increasing development and application of the multiple-quantum MAS NMR for half-integer quadrupole spins has led to various RF pulse sequences for improving the excitation of multiple-quantum cohe...


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