Chloro(triisopropyl)silane

Names

[ Name ]:
Chloro(triisopropyl)silane

[Synonym ]:
MFCD00009656
chloro-tri(propan-2-yl)silane
Triisopropylsilyl chloride
Chlorotriisopropylsilane
Chloro(triisopropyl)silane
Silane, chlorotris(1-methylethyl)-
Triisopropylchlorosilane

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
199.1±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₉H₂₁ClSi

[ Molecular Weight ]:
192.801

[ Flash Point ]:
62.8±0.0 °C

[ Exact Mass ]:
192.110107

[ LogP ]:
4.81

[ Vapour Pressure ]:
0.5±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.421

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S27-S36/37/39-S36/39

[ RIDADR ]:
UN 2987 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Stereoselective [4 + 1] annulation reactions with silyl vinylketenes derived from Fischer carbene complexes.

J. Org. Chem. 71 , 6542, (2006)

Stable silyl vinylketenes were prepared via the thermal reaction of Fischer carbene complexes with triisopropylsilyl- or tert-butyldimethylsilyl-substituted alkynes. The ability of these silyl vinylke...

A. Khalafi-Nezhad et al.

Tetrahedron 56 , 7503, (2000)

J.M. Muchowski, D.R. Solas

Tetrahedron Lett. 24 , 3455, (1983)