Isopropyllithium
Names
[ CAS No. ]:
1888-75-1
[ Name ]:
Isopropyllithium
[Synonym ]:
Lithium Propane
Isopropyllithium solution
ISOPROPYLLITHIUM
EINECS 217-561-4
i-propyllithium
lithium propan-2-ide
MFCD02093613
propen-2-yl lithium
lithium,(1-methylethyl)
Chemical & Physical Properties
[ Density]:
0.632 g/mL at 25ºC
[ Boiling Point ]:
35-36ºC
[ Molecular Formula ]:
C3H7Li
[ Molecular Weight ]:
50.02870
[ Flash Point ]:
31 °F
[ Exact Mass ]:
50.07080
[ LogP ]:
1.36400
[ Storage condition ]:
2~8℃
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS07, GHS08, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H224-H304-H315-H318-H336-H411
[ Precautionary Statements ]:
P210-P261-P273-P280-P301 + P310-P305 + P351 + P338
[ Hazard Codes ]:
F+: Highly flammable;C: Corrosive;
[ Risk Phrases ]:
R12
[ Safety Phrases ]:
16-33-36/37/39-45
[ RIDADR ]:
UN 2924 3/PG 1
[ HS Code ]:
2931900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
J. Org. Chem. 71 , 8510, (2006)
Organolithium-induced alkylative ring opening of N-sulfonyl-protected aziridinyl ethers is described. The reactions were efficiently carried out with a variety of organolithiums, providing a promising...