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| 中文名 | 4-二乙基水杨醛 |
|---|---|
| 英文名 | germanium(ii) iodide |
| 中文别名 |
二碘化锗
二碘化锗(II) 碘化锗(II) |
| 英文别名 |
EINECS 236-998-1
MFCD00135537 diiodogermanium Germanium(II) iodide |
| 密度 | 5.37 g/mL at 25 °C(lit.) |
|---|---|
| 沸点 | 545°C |
| 熔点 | 460°C |
| 分子式 | GeH2I2 |
| 分子量 | 328.46500 |
| 精确质量 | 329.74600 |
| LogP | 1.61560 |
| 外观性状 | 黄色至金色片或粉末 |
| 储存条件 | 常温密闭，阴凉通风干燥 |
| 稳定性 | 常温常压下稳定 避免的物料 水分/潮湿 氧化物 光 .遇湿空气即水解，在干燥空气中稳定。在氨溶液中就生成亚胺锗。二碘化锗稍溶于冷的氢碘酸，加热就非常易溶，所以能够重结晶。在真空中于240℃升华。二碘化锗可用作有机锗化物的合成原料。 |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10-24cm3）：无可用的 7、单一同位素质量：329.745748 Da 8、标称质量：330 Da 9、平均质量：328.4648 Da |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:0 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:3 8.表面电荷:0 9.复杂度:2.8 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：具有黄棕色光泽的六方晶系片状结晶。 2. 密度（g/mL,25/4℃）：5.37 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：不适用的 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：分解 |
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Section 1: Product Identification Chemical Name:Germanium (II) iodide (99.99+%-Ge) PURATREM CAS Registry Number:13573-08-5 Formula:GeI2 EINECS Number:236-998-1 Chemical Family:metal halide Synonym:Germanium diiodide
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound13573-08-5100%no datano data Section 3: Hazards Identification Severe irritant to skin, eyes and respiratory tract. Material hydrolyzes in contact with moisture releasing Emergency Overview: hydroiodic acid and under some conditions corrosive hydrogen iodide vapors. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:Causes severe irritation to the eyes. Skin Contact:Causes severe irritation of the skin with redness, pain, itching, pimples, boils, hives and blisters. Forms hydroiodic acid in the presence of moisture. Inhalation of vapors leads to irritation of the respiratory Inhalation: tract. Ingestion:Severe irritation of the Gastrointestinal system may occur. Acute Health Affects:Irritating to skin, eyes and respiratory tract. May cause dyspnea (breathing difficulty), and pulmonary edema. Chronic ingestion of iodides may produce iodism. Symptoms include skin rash, running nose, headache and Chronic Health Affects: irritation of mucous membranes. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:none required If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit corrosive hydrogen fluoride fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures To avoid raising dust, small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate Spill and Leak Procedures: and swept up. SECTION 7: Handling and Storage Store material in a tightly sealed bottle away from moisture. If possible, handle material in an efficient fume Handling and Storage: hood. Prolonged exposure to the atmosphere may lead to degradation of the product. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:If possible, handle the material in an efficient fume hood. If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators Respirator: requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:-10 mesh yellow pwdr. Molecular Weight:326.4 Melting Point:dec. Boiling Point:no data Vapor Pressure:no data Specific Gravity:5.73 Odor:not determined Solubility in Water:Decomposes in water SECTION 10: Stability and Reactivity Stability:moisture sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:contact with moisture Incompatibility:Oxidizing agents, halogens and active metals Decomposition Products:with moisture: hydroiodic acid and germanium oxides SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 1、急性毒性：主要的刺激性影响： 在皮肤上面：在皮肤和粘膜上造成腐蚀性影响，刺激皮肤和粘膜； 在眼睛上面：强烈的腐蚀性影响，刺激的影响；没有已知的敏化影响。 生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。
|
| 符号 |
GHS05 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H314 |
| 警示性声明 | P280-P305 + P351 + P338-P310 |
| 个人防护装备 | Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
| 危害码 (欧洲) | C: Corrosive; |
| 风险声明 (欧洲) | R34 |
| 安全声明 (欧洲) | S23-S26-S27-S36/37/39-S45 |
| 危险品运输编码 | UN 3260 8/PG 2 |
| WGK德国 | 3 |
| 包装等级 | II |
| 危险类别 | 8 |
|
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13573-08-5 |
| 文献：Journal of Chemical Physics, , vol. 91, # 5 p. 2834 - 2839 |
