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| 中文名 | 2-(羟甲基)-4-苄基吗啉 |
|---|---|
| 英文名 | 4-Benzyl-2-(hydroxymethyl)morpholine |
| 中文别名 | (4-苄基吗啉-2-基)甲醇 |
| 英文别名 |
(4-Benzyl-1,4-oxazinan-2-yl)methanol
2-Hydroxymethyl-4-benzylmorpholine (4-Benzyl-2-morpholinyl)methanol MFCD02682009 (4-benzylmorpholin-2-yl)methanol 2-Morpholinemethanol, 4-(phenylmethyl)- |
| 密度 | 1.1±0.1 g/cm3 |
|---|---|
| 沸点 | 303.2±27.0 °C at 760 mmHg |
| 分子式 | C12H17NO2 |
| 分子量 | 207.269 |
| 闪点 | 137.2±23.7 °C |
| 精确质量 | 207.125931 |
| PSA | 32.70000 |
| LogP | 0.76 |
| 外观性状 | 绿色油状 |
| 蒸汽压 | 0.0±0.7 mmHg at 25°C |
| 折射率 | 1.549 |
| 储存条件 | 2-8°C |
Synonym:N-Benzyl-(3-hydroxymethyl)morpholine Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 40987-24-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous liquid Color: colorless Odor: characteristic odor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 114 - 116 deg C @0.05mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Specific Gravity/Density: Molecular Formula: C12H17NO2 Molecular Weight: 207 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Bases, acids, oxidizing agents, acid chlorides. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 40987-24-4 unlisted. LD50/LC50: Not available. Carcinogenicity: (4-Benzyl-1,4-oxazinan-2-yl)methanol - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 40987-24-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 40987-24-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 40987-24-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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~70%
40987-24-4 |
| 文献：SANOFI; Brollo, Maurice; Carry, Jean-Christophe; Certal, Victor; Didier, Eric; Doerflinger, Gilles; EL Ahmad, Youssef; Filoche-Romme, Bruno; Halley, Frank; Karlsson, Karl Andreas; Schio, Laurent; Thompson, Fabienne Patent: US2013/274253 A1, 2013 ; Location in patent: Paragraph 1825-1826 ; |
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40987-24-4 |
| 文献：ABBOTT LABORATORIES Patent: US2010/63022 A1, 2010 ; Location in patent: Page/Page column 29 ; US 20100063022 A1 |
|
~24%
40987-24-4 |
| 文献：Henegar, Kevin E. Journal of Organic Chemistry, 2008 , vol. 73, # 9 p. 3662 - 3665 |
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40987-24-4 |
| 文献：Dobrev, Alexander; Nechev, Lubomir; Ivanov, Christo; Bon, Maryse Journal of Chemical Research, Miniprint, 1999 , # 3 p. 1001 - 1047 |
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~%
40987-24-4 |
| 文献：SANOFI; Brollo, Maurice; Carry, Jean-Christophe; Certal, Victor; Didier, Eric; Doerflinger, Gilles; EL Ahmad, Youssef; Filoche-Romme, Bruno; Halley, Frank; Karlsson, Karl Andreas; Schio, Laurent; Thompson, Fabienne Patent: US2013/274253 A1, 2013 ; |
|
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40987-24-4 |
| 文献：SANOFI; Brollo, Maurice; Carry, Jean-Christophe; Certal, Victor; Didier, Eric; Doerflinger, Gilles; EL Ahmad, Youssef; Filoche-Romme, Bruno; Halley, Frank; Karlsson, Karl Andreas; Schio, Laurent; Thompson, Fabienne Patent: US2013/274253 A1, 2013 ; |
