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| 中文名 | 碘化镍水合物 |
|---|---|
| 英文名 | nickel iodide |
| 英文别名 | nickel iodide hydrate |
| 分子式 | H12I2NiO6 |
|---|---|
| 分子量 | 420.59400 |
| 精确质量 | 419.80800 |
| PSA | 55.38000 |
| LogP | 1.38560 |
| 储存条件 | 室温，干燥，密封 |
| 稳定性 | 在空气中迅速潮解变成褐色并游离出碘。加热至43℃时,尚可存在,但在水浴上加热即变成无水物。 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:1 3.氢键受体数量:3 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积1 7.重原子数量:4 8.表面电荷:0 9.复杂度:0 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:4 |
| 更多 | 性状：蓝绿色结晶。 密度（g/mL,25/4℃）：不可用 相对蒸汽密度（g/mL,空气=1）：不可用 熔点（ºC）：不可用 沸点（ºC,常压）：不可用 沸点（ºC,5.2kPa）：不可用 折射率：不可用 闪点（ºC）：不可用 比旋光度（º）：不可用 自燃点或引燃温度（ºC）：不可用 蒸气压（kPa,25ºC）：不可用 饱和蒸气压（kPa,60ºC）：不可用 燃烧热（KJ/mol）：不可用 临界温度（ºC）：不可用 临界压力（KPa）：不可用 油水（辛醇/水）分配系数的对数值：不可用 爆炸上限（%,V/V）：不可用 爆炸下限（%,V/V）：不可用 溶解性：不可用 |
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Section 1: Product Identification Chemical Name:Nickel (II) iodide hydrate CAS Registry Number:7790-34-3 Formula:NiI2.XH2O EINECS Number:none Chemical Family:metal halide Synonym:Nickel diiodide hydrate, Nickelous iodide hydrate
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound7790-34-3100%0.1mg/m3 (as Ni)1mg/m3 (as Ni) Section 3: Hazards Identification Ingestion of nickel salts may cause intestinal disorders, convulsions, and asphyxia. Irritating to skin, eyes and Emergency Overview: respiratory tract. May cause cancer. Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust. Eye Contact:Causes slight to mild irritation of the eyes. Irritating to skin. May cause redness, itching, pimples, boils, hives and blisters. Prolonged contact may lead to Skin Contact: dermatitis. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion of nickel salts may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and Ingestion: convulsions. Irritating to skin, eyes and respiratory tract. May cause intestinal disorders, convulsions, asphyxia, Acute Health Affects: sensitization dermatitis, allergic asthma and pneumonitis. May cause cancer. Chronic ingestion of iodides may produce iodism. Symptoms include skin rash, running Chronic Health Affects: nose, headache and irritation of mucous membranes. NTP:Yes IARC:Yes OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:None. Material is non-flammable. Special Fire Fighting Procedures:No special fire fighting procedures required. Hazardous Combustion andnone Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable Spill and Leak Procedures: inert material and swept up. SECTION 7: Handling and Storage Handling and Storage:Store solid in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators Respirator: requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:green xtl. Molecular Weight:312.52 Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water: SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:active metals, bromine and chlorine Decomposition Products:water and metal iodide SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:Carcinogen (as Ni) Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound: See Category Code N495 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 急性毒性：不可用。 生态学数据: 1、其它有害作用：该物质对环境可能有危害，对水体应给予特别注意。
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| 危害码 (欧洲) | Xi |
|---|---|
| 风险声明 (欧洲) | 42/43-45-61 |
| 安全声明 (欧洲) | 22-26-36/37/39 |
| 危险品运输编码 | UN 3288 |