14434-22-1

• 常用中文名：亚铁氰化钠 十水合物
• 常用英文名：Iron(2+) sodium cyanide hydrate (1:4:6:10)
• CAS号：14434-22-1
• 分子式：C₆H₂₀FeN₆Na₄O₁₀
• 分子量：484.061
• 相关类别： 无机化工 无机盐 氰化物、氰氧化物及氰络合物
• 发布时间：2018-07-07 18:28:32
• 更新时间：2024-01-09 16:53:29

名称

• 中文名: 黄血盐钠
• 英文名: Sodium ferrocyanide
• 中文别名: 亚铁氰化钠十水合物; 六氰基铁(II)酸钠十水合物; 六氰基铁(II)酸钠
• 英文别名: YELLOW PRUSSIATE OF SODA DECAHYDRATE; Iron(2+) sodium cyanide hydrate (1:4:6:10); SODIUM FERROCYANIDE DECAHYDRATE; Sodiumferrocyanide; MFCD00149274; Sodium hexacyanoferrate(II) decahydrate; Tetrasodium hexacyanoferrate decahydrate; EINECS 237-081-9; Sodium Ferrocyanide

物化性质

• 密度: 1,458 g/cm3
• 沸点: 25.7ºC at 760mmHg
• 分子式: C₆H₂₀FeN₆Na₄O₁₀
• 分子量: 484.061
• 闪点: 435°C
• 精确质量: 484.018127
• PSA: 235.04000
• 外观性状: 固体
• 蒸汽压: 740mmHg at 25°C
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 水溶解性: soluble
• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:10

  3.氢键受体数量:22

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积153

  7.重原子数量:27

  8.表面电荷:0

  9.复杂度:127

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:21

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：1.458

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：无可用

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：435

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：可溶于水

MSDS

Section 1: Product Identification Chemical Name:Sodium hexacyanoferrate (II) decahydrate CAS Registry Number:14434-22-1 Formula:Na4Fe(CN)6.10H2O EINECS Number:237-081-9 Chemical Family:metal cyano complex Synonym:Sodium ferrocyanide decahydrate; Ferrate(4-), hexacyano-, sodium Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound14434-22-1100%1mg/m3 (as Fe - soluble)10mg/m3 (as Fe) Section 3: Hazards Identification May be irritating to skin, eyes and respiratory tract. May be harmful through inhalation, ingestion and skin Emergency Overview: absorption. Primary Routes of Exposure:Ingestion, inhalation, skin. Eye Contact:May cause mild to moderate irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Inhalation:May be irritating to the nose, mucous membranes and respiratory tract. Ingestion:Approved by the FDA as an anti-caking additive to table salt in low concentration. Acute Health Affects:May be irritating to skin, eyes and respiratory tract. No information available on long term chronic effects. Hexacyanoferrate passes through the body with only Chronic Health Affects: slight dissociation. Z NATURFORSCH SECT C BIOSCI; 45 (6). 1990. 681-690 NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical Skin Exposure: assistance if irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire, toxic oxidation or decomposition products may form. Decomposion Products: Unusual Fire or Explosion Hazards: Non-flammable. No unusual fire or explosion hazard. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Sweep up the solid and dispose of properly. SECTION 7: Handling and Storage Handling and Storage:No special storage conditions required. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Handle the material in an efficient fume hood. Reaction with mineral acids can release toxic fumes of Ventilation: hydrogen cyanide. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Handle the material in an efficient fume hood. Reaction with mineral acids can release toxic fumes of Ventilation: hydrogen cyanide. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:pale yellow xtl. Molecular Weight:303.88 (484.04) Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:1.458 Odor:none Solubility in Water:31.8g/100cc (20C) SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:No hazardous polymerization Conditions to Avoid:Do not heat with strong mineral acid. Incompatibility:oxidizing agents, mineral acids, halogens and active metals. Decomposition Products:iron oxide, nitrogen oxides and sodium oxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): R32
• 安全声明 (欧洲): S22-S24/25-S36-S26
• 海关编码: 2837200090

海关

海关编码	2837200090