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| 中文名 | 甘氨酸钠 |
|---|---|
| 英文名 | sodium glycinate |
| 中文别名 |
甘氨酸单钠盐
氨基乙酸钠 |
| 英文别名 |
Glycine sodium salt
Glycine, monosodium salt Sodium Glycinate Sodium aminoacetate MFCD00062543 Glycine monosodium salt Glycine, sodium salt (1:1) EINECS 227-842-3 sodium,2-aminoacetate |
| 描述 | 2-氨基乙酸钠是甘氨酸(HY-Y0966)衍生物[1]。 |
|---|---|
| 相关类别 | |
| 体外研究 | 氨基酸和氨基酸衍生物已被商业化用作能量补充剂。它们影响合成代谢激素的分泌、运动期间的燃料供应、压力相关任务期间的精神表现,并防止运动引起的肌肉损伤。它们被认为是有益的能生膳食物质[1]。 |
| 参考文献 |
| 密度 | 1.014g/cm3 |
|---|---|
| 沸点 | 240.9ºC at 760 mmHg |
| 熔点 | 290ºC decomposes |
| 分子式 | C2H4NNaO2 |
| 分子量 | 97.048 |
| 闪点 | 99.5ºC |
| 精确质量 | 97.013969 |
| PSA | 66.15000 |
| 外观性状 | 白色至灰白色结晶粉末 |
| 折射率 | 1.491 |
| 储存条件 | 室温 |
Synonym:Sodium Glycinate; Sodium Aminoacetate; Sodium Glycocollate Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. The toxicological properties of this material have not been fully investigated. Skin: May cause skin irritation. The toxicological properties of this material have not been fully investigated. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 6000-44-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Chunks Color: white granular Odor: Traces of NH3 pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 197 - 201 deg C Autoignition Temperature: Not available. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: SOLUBILITY IN METHANOL: 60 G/L (20C) Specific Gravity/Density: Molecular Formula: C2H4NO2Na.xH2O Molecular Weight: 97.05 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, dust generation, excess heat. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, ammonia. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 6000-44-8: MC1100000 LD50/LC50: Not available. Carcinogenicity: Glycine, Sodium Salt Hydrate - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 6000-44-8: No information available. Canada CAS# 6000-44-8 is listed on Canada's DSL List. CAS# 6000-44-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 6000-44-8 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
|
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
| 危害码 (欧洲) | C |
|---|---|
| RTECS号 | MC1100000 |
| 海关编码 | 2922499990 |
|
~99%
6000-44-8 |
| 文献：Thalhammer, Franz; Gastner, Thomas Patent: US2009/163739 A1, 2009 ; Location in patent: Page/Page column 2-3 ; |
|
~98%
6000-44-8 |
| 文献：UNILEVER PLC; UNILEVER N.V.; HINDUSTAN UNILEVER LIMITED; HARICHIAN, Bijan; AU, Van Patent: WO2013/14265 A1, 2013 ; Location in patent: Page/Page column 13-14 ; |
|
~%
6000-44-8 |
| 文献：JP2005/330225 A, ; Page/Page column 9 ; |
|
~%
6000-44-8 |
| 文献：Angewandte Chemie - International Edition, , vol. 51, # 45 p. 11306 - 11310 Angew. Chem., , p. 11468 - 11472 |
|
~%
6000-44-8 |
| 文献：Chemical and Pharmaceutical Bulletin, , vol. 29, # 7 p. 1998 - 2004 |
| 上游产品 5 | |
|---|---|
| 下游产品 10 | |
| 海关编码 | 2922499990 |
|---|---|
| 中文概述 | 2922499990 其他氨基酸及其酯及它们的盐（含有一种以上含氧基的除外）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装 |
| 监管条件 | A.入境货物通关单 B.出境货物通关单 |
| 检验检疫 | P.进境动植物、动植物产品检疫 Q.出境动植物、动植物产品检疫 R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验 |
| Summary | HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0% |
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