65039-08-9

• 常用中文名：1-乙基-3-甲基咪唑溴盐
• 常用英文名：1-Ethyl-3-methylimidazolium Bromide
• CAS号：65039-08-9
• 分子式：C₆H₁₁BrN₂
• 分子量：191.069
• 相关类别： 化学试剂 有机试剂 离子液体
• 发布时间：2018-07-16 14:18:10
• 更新时间：2024-01-02 17:55:13
• 【用途一】
  离子液体

名称

• 中文名: 1-乙基-3-甲基溴化咪唑
• 英文名: 1-Ethyl-3-methylimidazolium bromide
• 中文别名: 1-甲基-3-乙基咪唑溴盐; 1-乙基-3-甲基咪唑溴盐; 1-乙基-3-甲基溴化咪唑,溴化1-乙基-3-甲基咪唑; 溴化1-乙基-3-甲基咪唑
• 英文别名: 1-ethyl-3-methyl imidazolium bromide; MFCD03427610; 1-ethyl-3-methylimidazol-3-ium,bromide; 1-Ethyl-3-methylimidazolium Bromide; 3-Ethyl-1-methyl-1H-imidazol-3-ium bromide; 1H-imidazolium, 3-ethyl-1-methyl-, bromide (1:1); 1H-Imidazolium, 1-ethyl-3-methyl-, bromide (1:1); 1-Ethyl-3-methyl-1H-imidazol-3-ium bromide

物化性质

• 熔点: 70-73°C
• 分子式: C₆H₁₁BrN₂
• 分子量: 191.069
• 精确质量: 190.010559
• PSA: 8.81000
• 外观性状: 淡黄色至黄色晶体,结晶粉末
• 储存条件:

  存放在密封容器内，并放在阴凉，干燥处。储存的地方必须远离氧化剂。避免湿气和水源。

• 稳定性:

  远离氧化物，水分和潮湿。

• 水溶解性: 水溶性：可溶；可溶于：甲醇,二氯甲烷
• 计算化学:

  1、 疏水参数计算参考值（XlogP）：

  2、 氢键供体数量：

  3、 氢键受体数量：

  4、 可旋转化学键数量：

  5、 拓扑分子极性表面积（TPSA）：

  6、 重原子数量：

  7、 表面电荷：

  8、 复杂度：

  9、 同位素原子数量：0

  10、 确定原子立构中心数量：0

  11、 不确定原子立构中心数量：0

  12、 确定化学键立构中心数量：0

  13、 不确定化学键立构中心数量：0

  14、 共价键单元数量：1

• 更多:

  1. 性状：白色或者奶油色晶状体粉末。

  2. 密度（g/mL,25/4℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定。

MSDS

Name: 1-Ethyl-3-Methylimidazolium Bromide Material Safety Data Sheet Synonym: None Known CAS: 65039-08-9 Section 1 - Chemical Product MSDS Name:1-Ethyl-3-Methylimidazolium Bromide Material Safety Data Sheet Synonym:None Known Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 65039-08-9 1-Ethyl-3-Methylimidazolium Bromide ca. 100 unlisted Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs moisture from the air). Potential Health Effects Eye: Causes eye irritation. May cause chemical conjunctivitis. Skin: Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse. Storage: Store in a cool, dry place. Store in a tightly closed container. Store protected from moisture. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 65039-08-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Not available. Molecular Formula: C6H11BrN2 Molecular Weight: 191.07 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Hygroscopic: absorbs moisture or water from the air. Conditions to Avoid: Incompatible materials, excess heat, exposure to moist air or water. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 65039-08-9 unlisted. LD50/LC50: Not available. Carcinogenicity: 1-Ethyl-3-Methylimidazolium Bromide - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 65039-08-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 65039-08-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 65039-08-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 对水是危害的，不要让该产品接触地下水，水道污水系统，即使是小量该产品渗入地下水也会对饮用水造成危害，对水中有机物质有毒。若无政府许可，勿将材料排入周围环境。

安全

• 危害码 (欧洲): Xn:Harmful
• 风险声明 (欧洲): R22;R36/37/38
• 安全声明 (欧洲): S26-S37/39
• WGK德国: 3
• 海关编码: 2933290090

合成路线

616-47-7 74-96-4 ~99% 65039-08-9

文献：Angewandte Chemie - International Edition, , vol. 51, # 46 p. 11483 - 11486 Angew. Chem., , vol. 124, # 46 p. 11650 - 11654,5

143314-17-4 74-95-3 ~0% 628-51-3 65039-08-9

文献：EP2532646 A1, ; Page/Page column 5-7 ;

143314-17-4 106-93-4 ~0% 111-55-7 65039-08-9

文献：EP2532646 A1, ; Page/Page column 5-7 ;

78-76-2 143314-17-4 ~0% 105-46-4 65039-08-9

文献：EP2532646 A1, ; Page/Page column 5-7 ;

616-47-7 105-58-8 ~% 65039-08-9

文献：Chemistry Letters, , vol. 39, # 10 p. 1112 - 1113

7098-07-9 74-83-9 ~72% 65039-08-9

文献：Collection of Czechoslovak Chemical Communications, , vol. 48, # 1 p. 103 - 111

上下游产品

上游产品  9
616-47-7 74-96-4 143314-17-4 74-95-3
106-93-4 78-76-2 105-58-8 7098-07-9
74-83-9
下游产品  10
331717-63-6 174501-65-6 616-47-7 7098-07-9
143314-14-1 143314-17-4 143314-16-3 155371-19-0
174899-82-2 947601-94-7

海关

海关编码	2933290090
中文概述	2933290090. 其他结构含非稠合咪唑环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
Summary	2933290090. other compounds containing an unfused imidazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%