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| 中文名 | 溴化铑(III) |
|---|---|
| 英文名 | rhodium(3+),tribromide |
| 英文别名 |
Rhodium tribromide
EINECS 239-687-9 Rhodium bromide Rhodiumtribromid |
| 分子式 | Br3H4O2Rh |
|---|---|
| 分子量 | 378.64800 |
| 精确质量 | 375.68200 |
| PSA | 18.46000 |
| LogP | 2.40820 |
| 储存条件 | 密闭于阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。可溶于水的溴化铑可能在其晶格中含有氢氧根离子。 |
| 分子结构 | 1、摩尔折射率：无可用 2、 摩尔体积（cm3/mol）：无可用 3、 等张比容（90.2K）：无可用 4、 表面张力（dyne/cm）：无可用 5、 极化率：无可用 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:3 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:4 8.表面电荷:0 9.复杂度:0 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:4 |
| 更多 | 1. 性状：高温下生成的无水溴化铑为红棕色晶体，单斜系结晶 2. 密度（g/mL,25/4℃）：5.59 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：无可用 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
|
Section 1: Product Identification Chemical Name:Rhodium (III) bromide dihydrate CAS Registry Number:15608-29-4 Formula:RhBr3.2H2O EINECS Number:none Chemical Family:metal halide Synonym:Rhodium tribromide
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound15608-29-4100%0.01mg/m3 (as Rh0.001mg/m3 (as Rh Section 3: Hazards Identification No notable hazards reported for this material. Unrecognized hazards may be present. Dust may be irritating to Emergency Overview: the respiratory tract, skin and eyes. May be harmful if swallowed. Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust. Eye Contact:May be a mild irritant to the eyes. Skin Contact:May cause slight irritation of the skin. Inhalation:Inhalation of dust can lead to irritation of the respiratory tract. Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions. Acute Health Affects:May be irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:none required Special Fire Fighting Procedures:No special fire fighting procedures required. Hazardous Combustion andnone Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable Spill and Leak Procedures: inert material and swept up. SECTION 7: Handling and Storage Handling and Storage:Store solid in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:If possible, handle the material in an efficient fume hood. If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators Respirator: requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:brown to black xtl. Molecular Weight:342.63 (378.66) Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:Pungent odor. Solubility in Water:soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:chlorine and active metals Decomposition Products:none SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
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| 危险品运输编码 | UN 3288 |
|---|---|
| 包装等级 | III |
| 危险类别 | 6.1(b) |
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~%
15608-29-4 |
| 文献：Z. Anorg. Chem., , vol. 95, p. 249 - 249 |
|
~%
15608-29-4 |
| 文献：Rh: MVol., 15, page 42 - 44 Z. Anorg. Chem., , vol. 95, p. 249 - 249 |
|
~%
15608-29-4 |
| 文献：Inorganica Chimica Acta, , vol. 182, p. 19 - 24 |
| 上游产品 4 | |
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| 下游产品 0 | |
