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| 中文名 | 2-三丁基甲锡烷基噻唑 |
|---|---|
| 英文名 | tributyl(1,3-thiazol-2-yl)stannane |
| 中文别名 | 2-(三丁基锡烷基)噻唑 |
| 英文别名 |
2-(Tributylstannyl)-1,3-thiazole
tributylstannylthiazole 2-tributylstannanyl-thiazole 2-(1,1,1-tributylstannyl)-1,3-thiazole 2-(Tributylstannyl)thiazole 2-(tri-n-butylstannyl)thiazole Thiazole, 2-(tributylstannyl)- thiazole-2-SnBu3 2-(tributylstannanyl)-1,3-thiazole MFCD01319057 Thiazole,2-(tributylstannyl) (1,3-Thiazol-2-yl)tributylstannane |
| 密度 | 1.1900 g/mL at 25ºC(lit.) |
|---|---|
| 沸点 | 361.7±25.0 °C at 760 mmHg |
| 熔点 | 307-309ºC(lit.) |
| 分子式 | C15H29NSSn |
| 分子量 | 374.172 |
| 闪点 | 172.6±23.2 °C |
| 精确质量 | 375.104279 |
| PSA | 41.13000 |
| LogP | 9.19 |
| 蒸汽压 | 0.0±0.8 mmHg at 25°C |
| 折射率 | n20/D 1.5200(lit.) |
| 储存条件 | 密封保存。 |
| 稳定性 | 常温常压性质稳定。避免与强氧化剂、强矿物酸接触。 |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10-24cm3）：无可用的 7、单一同位素质量：375.104269 Da 8、标称质量：375 Da 9、平均质量：374.1725 Da |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:2 4.可旋转化学键数量:10 5.互变异构体数量:无 6.拓扑分子极性表面积41.1 7.重原子数量:18 8.表面电荷:0 9.复杂度:189 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：未确定 2. 密度（g/mL,25℃）：1.1900 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：307-309 6. 沸点（ºC, mmHg）：227-230 7. 折射率：1.5200 8. 闪点（ºC）：>110 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）: 未确定 11. 蒸气压（mmHg,20ºC）：未确定 12. 饱和蒸气压（kPa, 20ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE Product name: 2-Tributylstannylthiazole Section2. HAZARDS IDENTIFICATION Classification of the substance or mixture According to Regulation (EC) No1272/2008 Acute toxicity, Dermal (Category 4) Acute toxicity, Oral (Category 3)
Skin irritation (Category 2) Eye irritation (Category 2) Specific target organ toxicity - repeated exposure (Category 1) Acute aquatic toxicity (Category 1) According to European Directive 67/548/EEC as amended. Toxic if swallowed. Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Harmful in contact with skin. Irritating to eyes and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Label elements Pictogram Signal wordDanger Hazard statement(s) H301Toxic if swallowed. H312Harmful in contact with skin. H315Causes skin irritation. H319Causes serious eye irritation. H372Causes damage to organs through prolonged or repeated exposure. H400Very toxic to aquatic life. Precautionary statement(s) P273Avoid release to the environment. P280Wear protective gloves/protective clothing. P301 + P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314Get medical advice/attention if you feel unwell. Hazard symbol(s) TToxic NDangerous for the environment R-phrase(s) R21Harmful in contact with skin. R25Toxic if swallowed. R36/38Irritating to eyes and skin. R48/23/25Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R50/53Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S35This material and its container must be disposed of in a safe way. S36/37/39Wear suitable protective clothing, gloves and eye/face protection. S45In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60This material and its container must be disposed of as hazardous waste. S61Avoid release to the environment. Refer to special instructions/ Safety data sheets. Other hazards - none Section3. COMPOSITION/INFORMATION ON INGREDIENTS Formula: C15H29NSSn Molecular Weight: 374,17 g/mol CAS-No.EC-No.Index-No.ClassificationConcentration 2-Tributylstannylthiazole 121359-48-6-050-008-00-3Acute Tox. 4; Acute Tox. 3;- Skin Irrit. 2; Eye Irrit. 2; STOT RE 1; Aquatic Acute 1; H301, H312, H315, H319, H372, H400 T, N, R21 - R25 - R36/38 - R48/23/25 - R50/53 For the full text of the H-Statements mentioned in this Section, see Section 16. Section4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Section5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. Section6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Section7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Normal measures for preventive fire protection. Conditions for safe storage Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Handle with gloves. Eye protection Face shield and safety glasses Skin and body protection Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Section9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Formliquid Colourcolourless Safety data pHno data available Melting pointno data available Boiling point307 - 309 °C - lit. Flash point> 110 °C - closed cup Ignition temperatureno data available Lower explosion limitno data available Upper explosion limitno data available Density1,19 g/cm3 at 25 °C Water solubilityno data available Section10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Conditions to avoid no data available Materials to avoid Strong oxidizing agentsStrong oxidizing agents, Strong mineral acids, Bases Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx), Sulphur oxides, Tin/tin oxides Section11. TOXICOLOGICAL INFORMATION Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure Causes damage to organs through prolonged or repeated exposure. Aspiration hazard no data available Potential health effects InhalationToxic if inhaled. May cause respiratory tract irritation. IngestionToxic if swallowed. Skin Harmful if absorbed through skin. Causes skin irritation. EyesCauses eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: no data available Section12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available PBT and vPvB assessment no data available Other adverse effects Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Section13. DISPOSAL CONSIDERATIONS Product Observe all federal, state, and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. Section14. TRANSPORT INFORMATION ADR/RID UN-Number: 2788 Class: 6.1Packing group: II Proper shipping name: ORGANOTIN COMPOUND, LIQUID, N.O.S. (2-Tributylstannylthiazole) IMDG UN-Number: 2788 Class: 6.1Packing group: IIEMS-No: F-A, S-A Proper shipping name: ORGANOTIN COMPOUND, LIQUID, N.O.S. (2-Tributylstannylthiazole) Marine pollutant: Marine pollutant IATA UN-Number: 2788 Class: 6.1Packing group: II Proper shipping name: Organotin compound, liquid, n.o.s. (2-Tributylstannylthiazole) Section15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Section16. OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Acute Tox.Acute toxicity Aquatic AcuteAcute aquatic toxicity Eye Irrit.Eye irritation H301Toxic if swallowed. H312Harmful in contact with skin. H315Causes skin irritation. H319Causes serious eye irritation. H372Causes damage to organs through prolonged or repeated exposure. H400Very toxic to aquatic life. Skin Irrit.Skin irritation STOT RESpecific target organ toxicity - repeated exposure NDangerous for the environment TToxic R21Harmful in contact with skin. R25Toxic if swallowed. R36/38Irritating to eyes and skin. R48/23/25Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R50/53Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Further information Copyright 2010 Co. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Co., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. |
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毒理学数据: 刺激粘膜和上层呼吸道。对眼睛和皮肤有刺激。吸入，摄入或皮肤吸收可能是有害的。
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| 符号 |
GHS06, GHS08, GHS09 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H301-H312-H315-H319-H372-H400 |
| 警示性声明 | P273-P280-P301 + P310-P305 + P351 + P338-P314 |
| 个人防护装备 | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | T: Toxic;N: Dangerous for the environment; |
| 风险声明 (欧洲) | R21 |
| 安全声明 (欧洲) | 35-36/37/39-45-60-61 |
| 危险品运输编码 | UN 2788 6.1/PG 2 |
| 海关编码 | 2934100090 |
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~98%
121359-48-6 |
| 文献：King Abdulaziz City for Science and Technology; Karim, Mohammad Rezaul; Akhtaruzzaman, Md.; Islam, Ashraful; Al-Ahmari, Abdulrahman M. Patent: US8575355 B2, 2013 ; Location in patent: Paragraph 0032 ; |
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~97%
121359-48-6 |
| 文献：ELAN PHARMACEUTICALS, INC.; GALEMMO, Robert, A., Jr.; ARTIS, Dean, Richard; YE, Xiaocong, Michael; AUBELE, Danielle, L.; TRUONG, Anh, P.; BOWERS, Simeon; HOM, Roy, K.; ZHU, Yong-Liang; NEITZ, R., Jeffrey; SEALY, Jennifer; ADLER, Marc; BEROZA, Paul; ANDERSON, John, P. Patent: WO2011/79114 A1, 2011 ; Location in patent: Page/Page column 125 ; WO 2011/079114 A1 |
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~%
121359-48-6 |
| 文献：WO2003/87104 A1, ; Page/Page column 14 ; WO 03/087104 A1 |
| 上游产品 3 | |
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| 下游产品 0 | |
| 海关编码 | 2934100090 |
|---|---|
| 中文概述 | 2934100090. 结构上含有一个非稠合噻唑环的化合物(不论是否氢化). 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0% |
