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| 中文名 | 三-I-丙基氯化锡 |
|---|---|
| 英文名 | chloro-tri(propan-2-yl)stannane |
| 中文别名 | 三异丙基氯化锡 |
| 英文别名 |
Triisopropyltin chloride
Chlorotriisopropylstannane Triisopropylzinnchlorid Triisopropylchlorostannane Stannane,chlorotriisopropyl Tri-i-propylzinnchlorid |
| 沸点 | 219.8ºC at 760mmHg |
|---|---|
| 分子式 | C9H21ClSn |
| 分子量 | 283.41700 |
| 闪点 | 86.7ºC |
| 精确质量 | 284.03500 |
| LogP | 4.40070 |
| 蒸汽压 | 0.173mmHg at 25°C |
| 储存条件 | 密闭于阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。 |
| 分子结构 | 1、摩尔折射率：无可用 2、 摩尔体积（cm3/mol）：无可用 3、 等张比容（90.2K）：无可用 4、 表面张力（dyne/cm）：无可用 5、 极化率：无可用 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:0 4.可旋转化学键数量:3 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:11 8.表面电荷:0 9.复杂度:97 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：无可用 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：无可用 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
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Section 1: Product Identification Chemical Name:Tri-i-propyltin chloride, min. 98% CAS Registry Number:14101-95-2 Formula:(C3H7)3SnCl EINECS Number:none Chemical Family:organotin compound Synonym:Chlorotriisopropylstannane, Chlorotriisopropyltin
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound14101-95-2100%0.1mg/m3 (Sn-org)0.1mg/m3 (Sn-org) Section 3: Hazards Identification Emergency Overview:Toxic if swallowed. Severe irritant by inhalation and in contact with skin. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:May cause severe irritation to the eyes. Skin Contact:May causes severe irritation of the skin. Forms hydrogen chloride upon exposure to the atmosphere. Inhalation may lead to irritation of the respiratory Inhalation: tract. Ingestion:Toxic if swallowed. Toxic by inhalation, in contact with skin and if swallowed. May be irritating to skin, eyes and respiratory tract. Acute Health Affects: May cause eye and skin burns, dyspnea (breathing difficulty) and pulmonary edema. Chronic Health Affects:No information on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit hydrochloric acid fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Store material in a tightly sealed container away from moisture. If possible, handle material in an efficient fume Handling and Storage: hood. Prolonged exposure to the atmosphere will lead to degradation of the product. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:colorless liquid Molecular Weight:283.43 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:not determined Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:strong oxidizing agents and halogens Decomposition Products:carbon monoxide, carbon dioxide, hydrochloric acid, organic fumes, and tin oxychlorides. SECTION 11: Toxicological Information RTECS Data:Oral(rat); LD50: 44mg/kg. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. SECTION 13: Disposal Considerations Disposal:Avoid release to the environment. Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Organotin compounds, Liquid, N.O.S. Hazard Class (CFR):6.1 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 2788 Shipping Name (IATA):Organotin compound, Liquid, N.O.S. Hazard Class (IATA):6.1 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 2788 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 试验方法：口服 生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
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| 海关编码 | 2931900090 |
|---|
|
~%
14101-95-2 |
| 文献：Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.4.3, page 92 - 93 |
|
~0%
详细
|
| 文献：Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.4.3, page 92 - 93 |
|
~%
14101-95-2 |
| 文献：Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.4, page 270 - 272 |
|
~%
14101-95-2 |
| 文献：Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.4, page 270 - 272 |
|
~%
14101-95-2 |
| 文献：Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.4, page 270 - 272 |
|
~%
14101-95-2 |
| 文献：Abraham, M. H.; Grellier, P. L. J. Chem. Soc. Perkin Trans. II, 1973 , p. 1132 - 1137 |
|
~%
14101-95-2 |
| 文献：Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.4.3, page 92 - 93 |
|
~%
14101-95-2 |
| 文献：Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.4.3, page 92 - 93 |
|
~%
14101-95-2 |
| 文献：Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.4, page 270 - 272 |
| 上游产品 4 | |
|---|---|
| 下游产品 1 | |
| 海关编码 | 2931900090 |
|---|---|
| 中文概述 | 2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0% |
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
