118612-00-3

• 常用中文名：N,N-二甲基苯铵四(五氟苯基)硼酸盐
• 常用英文名：Dimethylanilinium tetrakis(pentafluorophenyl)borate
• CAS号：118612-00-3
• 分子式：C₃₂H₁₁BF₂₀N-
• 分子量：801.223
• 相关类别： 有机原料 有机金属类化合物 有机铋、钴、镨、钆、镓、铱、铼、钇、铽等
• 发布时间：2018-12-27 15:51:34
• 更新时间：2024-01-11 19:12:03

• 1、 聚合反应催化剂

名称

• 中文名: N,N-二甲基苯铵四(五氟苯基)硼酸盐
• 英文名: Dimethylanilinium tetrakis (pentafluorophenyl)borate
• 中文别名: N，N-二甲基苯胺四（五氟苯）硼酸盐; 硼类催化剂
• 英文别名: Dimethylanilinium tetrakis(pentafluorophenyl)borate; N,N-Dimethylanilinium tetrakis(pentafluorophenyl)borate(1-); N,N-Dimethylanilinium Tetrakis(pentafluorophenyl)borate; EINECS 422-050-6

物化性质

• 熔点: 225.0 to 229.0 °C
• 分子式: C₃₂H₁₁BF₂₀N-
• 分子量: 801.223
• 精确质量: 801.074341
• PSA: 3.24000
• LogP: 7.59860
• 外观性状: 灰白色粉末,暴露在空气中颜色变蓝色
• 储存条件:

  保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置

• 稳定性:

  常温常压下稳定

• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：800.067068 Da

  8、标称质量：800 Da

  9、平均质量：800.2161 Da

• 更多:

  1. 性状：白色粉末

  2. 密度（g/mL,20℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,KPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（Pa,20ºC）：未确定

  12. 饱和蒸气压（KPa,20ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Section 1: Product Identification Chemical Name:N,N-Dimethylanilinium tetra(pentafluorophenyl)borate, 98% CAS Registry Number:118612-00-3 Formula:[C6H5N(CH3)2H]+[B(C6F5)4]- EINECS Number:none Chemical Family:organic or inorganic borate Synonym:Dimethylaniline, tetra(pentafluorophenyl)boric acid salt Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound118612-00-3100%2.5mg/m3 (as F)2.5mg/m3 (as F) Section 3: Hazards Identification The toxic effects of this compound have not been reported. Unrecognized hazards may be present. Irritating to Emergency Overview: the respiratory tract, skin and eyes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, inhalation, eyes and skin Eye Contact:Causes irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. May cause redness, itching and pain. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. No specific information is available on the physiological effects of ingestion. May cause gastrointestinal Ingestion: irritation, nausea, and vomiting. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate Chronic Health Affects:fluoride ion, causing, nausea, vomiting, labored breathing, hypocalcemia, deterioration of bone and tooth structure, kidney and liver damage. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry powder, water spray, or foam Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus Special Fire Fighting Procedures: and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry area away from heat and direct sunlight. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white to off-white powder Molecular Weight:801.23 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:Insoluble SECTION 10: Stability and Reactivity Stability:hygroscopic Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:Oxidizing agents Decomposition Products:carbon monoxide, nitrogen oxides, organic fumes, hydrogen fluoride, and carbonyl fluoride SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水是稍微有危害的，若无政府许可，勿将材料排入周围环境。

安全

• 危害码 (欧洲): Xn: Harmful;
• 风险声明 (欧洲): R20/21/22;R36/37/38
• 安全声明 (欧洲): 36/37/39-26-22