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| 中文名 | 10-氯-9-蒽甲醛 |
|---|---|
| 英文名 | 10-Chloro-9-anthraldehyde |
| 中文别名 | 10-氯蒽-9-甲醛 |
| 英文别名 |
EINECS 234-086-8
10-chloroanthracene-9-carbaldehyde MFCD00001255 |
| 密度 | 1.327g/cm3 |
|---|---|
| 沸点 | 435.9ºC at 760mmHg |
| 熔点 | 215-218ºC(lit.) |
| 分子式 | C15H9ClO |
| 分子量 | 240.68400 |
| 闪点 | 221.8ºC |
| 精确质量 | 240.03400 |
| PSA | 17.07000 |
| LogP | 4.45890 |
| 蒸汽压 | 8.46E-08mmHg at 25°C |
| 折射率 | 1.746 |
| 储存条件 | 密闭,阴凉干燥处保存，确保有良好的通风 |
| 稳定性 | 如果遵照规格使用和储存则不会分解，未有已知危险发生 避免强氧化剂 |
| 分子结构 | 1、 摩尔折射率：73.58 2、 摩尔体积（m3/mol）：181.2 3、 等张比容（90.2K）：495.8 4、 表面张力（dyne/cm）：55.9 5、 极化率（10-24cm3）：29.17 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:4.5 2.氢键供体数量:0 3.氢键受体数量:1 4.可旋转化学键数量:1 5.互变异构体数量:无 6.拓扑分子极性表面积17.1 7.重原子数量:17 8.表面电荷:0 9.复杂度:267 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1．性状：不可用 2．密度（g/mL,25/4℃）：不可用 3．相对蒸汽密度（g/mL,空气=1）：不可用 4．熔点（ºC）：215-218 5．沸点（ºC,常压）：不可用 6．沸点（ºC,5.2kPa）：不可用 7．折射率：不可用 8．闪点（ºC）：不可用 9．比旋光度（º）：不可用 10．自燃点或引燃温度（ºC）：不可用 11．蒸气压（kPa,25ºC）：不可用 12．饱和蒸气压（kPa,60ºC）：不可用 13．燃烧热（KJ/mol）：不可用 14．临界温度（ºC）：不可用 15．临界压力（KPa）：不可用 16．油水（辛醇/水）分配系数的对数值：不可用 17．爆炸上限（%,V/V）：不可用 18．爆炸下限（%,V/V）：不可用 19．溶解性：不可用 |
Synonym:None known Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 10527-16-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: yellow Odor: none reported pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 215.00 - 218.00 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C15H9ClO Molecular Weight: 240.69 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation, excess heat, strong oxidants. Incompatibilities with Other Materials: Strong bases, strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 10527-16-9 unlisted. LD50/LC50: Not available. Carcinogenicity: 10-Chloro-9-Anthraldehyde - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 10527-16-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 10527-16-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 10527-16-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 急性毒性：不可用。 生态学数据: 1、其它有害作用：该物质对环境可能有危害，对水体应给予特别注意。
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| 个人防护装备 | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
|---|---|
| 危害码 (欧洲) | Xi |
| 危险品运输编码 | NONH for all modes of transport |
| WGK德国 | 3 |
| 海关编码 | 2913000090 |
|
~88%
10527-16-9 |
| 文献：Achar, Tapas Kumar; Maiti, Saikat; Mal, Prasenjit RSC Advances, 2014 , vol. 4, # 25 p. 12834 - 12839 |
|
~89%
10527-16-9 |
| 文献：Bolton, Roger; Hibbert, Brynn D.; Parand, Simin Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 981 - 984 |
|
~78%
10527-16-9 |
| 文献：Ghosh, Kumaresh; Adhikari, Suman Journal of the Indian Chemical Society, 2008 , vol. 85, # 9 p. 959 - 961 |
|
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10527-16-9 |
| 文献：DE514415 , ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 17, p. 564 |
|
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| 文献：US1717567 , ; |
|
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| 文献：US1717567 , ; |
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| 上游产品 8 | |
|---|---|
| 下游产品 3 | |
| 海关编码 | 2913000090 |
|---|---|
| 中文概述 | 2913000090 品目2912所列产品的其他衍生物〔指卤化,磺化,硝化或亚硝化的衍生物〕. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0% |
