173831-50-0

173831-50-0结构式

常用中文名：(R)-2,2'-双(甲氧基甲氧基)-1,1'-联萘
常用英文名：2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
CAS号：173831-50-0
分子式：C₂₄H₂₂O₄
分子量：374.429
发布时间：2018-06-19 19:13:18
更新时间：2024-01-08 19:42:56

中文名	(R)-(+)-2,2’-双(甲氧基甲氧基)-1,1’-联萘
英文名	(R)-2,2’-Bis(methoxymethoxy)-1,1'-binaphthyl
中文别名	(R)-(+)-2,2'-双(甲氧基甲氧基)-1,1'-联萘 (R)-2,2'-双(甲氧基甲氧基)-1,1'-联萘 (R)-(+)-2,2'-双(甲氧基甲氧基)-1,1'-联萘 (R)-(+)-2,2-双(甲氧甲基)-1,1-二萘酚
英文别名	(R)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl (S)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL 2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene (R)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene 2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL (R)-(+)-2,2′-Bis(methoxymethoxy)-1,1′-binaphthyl MFCD03788935 1,1'-Binaphthalene, 2,2'-bis(methoxymethoxy)-

密度	1.2±0.1 g/cm3
沸点	477.8±45.0 °C at 760 mmHg
熔点	92-96ºC(lit.)
分子式	C₂₄H₂₂O₄
分子量	374.429
闪点	126.2±35.6 °C
精确质量	374.151794
PSA	36.92000
LogP	4.57
外观性状	固体;White to Light yellow powder to crystal
蒸汽压	0.0±1.1 mmHg at 25°C
折射率	1.630
储存条件	密闭于阴凉干燥环境中
稳定性	遵照规定使用和储存则不会分解。
水溶解性	可溶于：甲苯
分子结构	1、摩尔折射率：112.64 2、摩尔体积（m³/mol）：316.6 3、等张比容（90.2K）：820.5 4、表面张力（dyne/cm）：45.0 5、极化率（10^-24cm³）：44.65
计算化学	1.疏水参数计算参考值（XlogP）:5.9 2.氢键供体数量:0 3.氢键受体数量:4 4.可旋转化学键数量:7 5.互变异构体数量:无 6.拓扑分子极性表面积36.9 7.重原子数量:28 8.表面电荷:0 9.复杂度:428 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1
更多	1. 性状：无可用 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：92-96 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用

Section 1: Product Identification
Chemical Name:(R)-(+)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl, 98%
CAS Registry Number:173831-50-0
Formula:C24H22O4
EINECS Number:none
Chemical Family:organic alcohol

Synonym:(R)-(+)-2,2'-Bis-methoxymethoxy-[1,1']binaphthalenyl

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound173831-50-0100%no datano data

Section 3: Hazards Identification
Emergency Overview:Dust is irritating to the respiratory tract, skin, eyes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, eyes, inhalation
Eye Contact:Causes mild to moderate irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Dust is irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No specific information is available on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
Inhalation:
breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:dry chemical, carbon dioxide, water or foam.
If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes, carbon monoxide and carbon dioxide.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store the material in a tightly sealed container in a cool, dry place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white powder
Molecular Weight:374.43
Melting Point:100-103°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:not determined
Solubility in Water:slightly soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents
Decomposition Products:carbon monoxide, carbon dioxide and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none

SECTION 16 - ADDITIONAL INFORMATION
N/A

生态学数据:

该物质对环境可能有危害，对水体应给予特别注意。

符号	GHS05, GHS09
信号词	Danger
危害声明	H318-H410
警示性声明	P273-P280-P305 + P351 + P338-P501
个人防护装备	dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲)	Xi,N
风险声明 (欧洲)	R41
安全声明 (欧洲)	26-39-60-61-36/39-25
危险品运输编码	UN 3077 9/PG 3