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| 中文名 | 双(二乙基胺基)磷酰氯 |
|---|---|
| 英文名 | N-[chloro(diethylamino)phosphoryl]-N-ethylethanamine |
| 中文别名 | 双(二乙基氨基)氯酸偶膦 |
| 英文别名 |
Phosphorodiamidic chloride, N,N,N',N'-tetraethyl-
tetraethyl-phosphorodiamidic acid chloride tetraethylchlorophosphoramidate N,N,N',N'-Tetraethylphosphorodiamidic chloride tetraethyldiamidochlorophosphate MFCD00137958 EINECS 217-262-9 Bis(diethylamino)phosphoryl chloride Bis(diethylamino)phosphorochloridate Tetraethylphosphorodiamidic chloride |
| 密度 | 1.1±0.1 g/cm3 |
|---|---|
| 沸点 | 266.6±23.0 °C at 760 mmHg |
| 分子式 | C8H20ClN2OP |
| 分子量 | 226.684 |
| 闪点 | 115.0±22.6 °C |
| 精确质量 | 226.100174 |
| PSA | 33.36000 |
| LogP | 0.94 |
| 外观性状 | 透明无色至淡黄色液体 |
| 蒸汽压 | 0.0±0.5 mmHg at 25°C |
| 折射率 | 1.465 |
| 储存条件 | 在干爽惰性气体下密封贮藏，储存在阴凉、干燥的地方； 避免接触湿气和水源 |
| 稳定性 | 对湿气敏感；可与氧化剂和碱起反应 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:3 4.可旋转化学键数量:6 5.互变异构体数量:无 6.拓扑分子极性表面积23.6 7.重原子数量:13 8.表面电荷:0 9.复杂度:165 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：无色或灰黄色液体 2. 密度（g/mL,20 ºC）：1.07 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC /0.3mmHg）：101 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：1.466-1.468 8. 闪点（ºC/0.3mmHg）：101 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）未确定： 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：与水反应 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Causes burns.Moisture sensitive. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed. Inhalation: Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use and store under nitrogen. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Keep refrigerated. (Store below 4C/39F.) Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1794-24-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: pungent odor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 101 deg C @ .30mm H Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.0700g/cm3 Molecular Formula: Molecular Weight: 226.58 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, strong bases, amines, alcohols. Hazardous Decomposition Products: Hydrogen chloride, phosphine, carbon monoxide, oxides of nitrogen, oxides of phosphorus, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1794-24-7 unlisted. LD50/LC50: Not available. Carcinogenicity: Bis(diethylamino)phosphochloridate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: CORROSIVE LIQUID, N.O.S.* Hazard Class: 8 UN Number: 1760 Packing Group: II IMO Shipping Name: CORROSIVE LIQUID, N.O.S. Hazard Class: 8 UN Number: 1760 Packing Group: II RID/ADR Shipping Name: CORROSIVE LIQUID, N.O.S. Hazard Class: 8 UN Number: 1760 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 1794-24-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 1794-24-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1794-24-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 刺激眼睛、皮肤和粘膜并造成腐蚀性影响 生态学数据: 对水是稍微危害的，不要让未稀或大量产品进入地下水、水道或污水系统 若无政府许可，勿将材料排入周围环境。
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| 危害码 (欧洲) | C: Corrosive; |
|---|---|
| 风险声明 (欧洲) | R34 |
| 安全声明 (欧洲) | 45-36/37/39 |
| 危险品运输编码 | UN 1759 |
| 包装等级 | II |