查看所有供应商和价格请点击：
| 中文名 | 双(乙基环戊二烯)铬(II) |
|---|---|
| 英文名 | bis(ethylcyclopentadienyl)chromium |
| 中文别名 | 双(乙基环戊二烯基)铬 |
| 英文别名 |
1,1'-Diethylchromocene
MFCD01862449 |
| 密度 | 1.15 g/mL at 25ºC(lit.) |
|---|---|
| 分子式 | C14H18Cr |
| 分子量 | 238.28900 |
| 精确质量 | 238.08100 |
| LogP | 3.60340 |
| 储存条件 | 密闭于阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。 |
| 分子结构 | 1、摩尔折射率：无可用 2、 摩尔体积（cm3/mol）：无可用 3、 等张比容（90.2K）：无可用 4、 表面张力（dyne/cm）：无可用 5、 极化率：无可用 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:2 4.可旋转化学键数量:2 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:15 8.表面电荷:0 9.复杂度:42 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:3 |
| 更多 | 1. 性状：无可用 2. 密度（g/mL,25/4℃）：1.15 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：无可用 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
|
Section 1: Product Identification Chemical Name:Bis(ethylcyclopentadienyl)chromium, min. 98% CAS Registry Number:55940-03-9 Formula:[(C2H5)C5H4]2Cr EINECS Number:none Chemical Family:metallocene Synonym:1,1'-Diethylchromocene
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound55940-03-9100%0.5mg/m3 (as Cr)0.5mg/m3 (as Cr) Section 3: Hazards Identification Irritating to eyes, skin an respiratory tract. Harmful by inhalation, in contact with skin and if swallowed. Emergency Overview: Chromium (III), a possible metabolite, has acted as a tumorigen and mutagen in animal studies. Primary Routes of Exposure:Ingestion, inhalation of dust Eye Contact:Causes slight to mild irritation of the eyes Skin Contact:Causes slight to mild irritation of the skin. Harmful in contact with skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Harmful through inhalation. Ingestion:Harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Harmful through inhalation, in contact with skin and if swallowed. It is possible that prolonged exposure could result in formation of Chromium (III) salts in the human body. Chronic Health Affects:Although less toxic than Chromium (VI), some animal studies show Chromium (III) to act as a mutagen and tumorigen. NTP:Yes IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:none Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating and toxic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Store in a tightly sealed container. Handle and store under an inert atmosphere of nitrogen or argon. Handling and Storage: Exposure to air may result in degradation of the product. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:red liq. Molecular Weight:238.29 Melting Point:no data Boiling Point:95-98°C /1.0mm Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive liquid Hazardous Polymerization:none Contact with oxygen. Keep away from heat and ignition sources including open flame and electrostatic Conditions to Avoid: discharge. Incompatibility:strong oxidizing agents Decomposition Products:carbon dioxide, carbon monoxide, organic fumes and chromium oxide. SECTION 11: Toxicological Information RTECS Data:No information available from the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Self-heating liquid, Inorganic, N.O.S. Hazard Class (CFR):4.2 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 3186 Shipping Name (IATA):Self-heating liquid, Inorganic, N.O.S. Hazard Class (IATA):4.2 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 3186 SECTION 15: Regulatory Information TSCA:Not listed on the TSCA inventory SARA (Title 313):Title compound: see Category Code N090 for reporting Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
|
生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
|
| 符号 |
GHS02, GHS07 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H250-H302-H312-H315-H319-H332-H335 |
| 警示性声明 | P222-P231-P261-P280-P305 + P351 + P338-P422 |
| 个人防护装备 | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | F,Xn |
| 风险声明 (欧洲) | 17-20/21/22-36/37/38 |
| 安全声明 (欧洲) | S26-S36 |
| 危险品运输编码 | UN 2845 4.2/PG 1 |