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通常用200号汽油作溶剂制成溶液。用作油漆、油墨的催干剂。
| 中文名 | 2-乙基己基锰(II)溶液 |
|---|---|
| 英文名 | Manganese bis(2-ethylhexanoate) |
| 中文别名 | 异辛酸锰 |
| 英文别名 |
MFCD00058698
2-Ethylhexanoic acid - manganese (2:1) Hexanoic acid, 2-ethyl-, manganese salt (2:1) EINECS 236-562-0 |
| 密度 | 0.940 ---0.955 g/cm3 |
|---|---|
| 沸点 | 228ºC at 760 mmHg |
| 分子式 | C16H30MnO4 |
| 分子量 | 343.361 |
| 闪点 | 116.6ºC |
| 精确质量 | 343.168121 |
| PSA | 52.60000 |
| LogP | 4.42060 |
| 外观性状 | 液体 |
| 储存条件 | 常温密闭，阴凉通风干燥 |
| 稳定性 | 常温常压下稳定 避免的物料 氧化物 |
| 水溶解性 | Soluble in organic solvents. Not miscible or difficult to mix with water. |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10-24cm3）：无可用的 7、单一同位素质量：341.152458 Da 8、标称质量：341 Da 9、平均质量：341.345 Da |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:4 4.可旋转化学键数量:8 5.互变异构体数量:无 6.拓扑分子极性表面积80.3 7.重原子数量:21 8.表面电荷:0 9.复杂度:93.9 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:2 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:3 |
| 更多 | 1. 性状：黑色溶液 2. 密度（g/mL,25/4℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：42 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：不能拌和的或者难以拌和得 |
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Section 1: Product Identification Chemical Name:Manganese (II) 2-ethylhexanoate, 40% solution in mineral spirits (6% Mn) CAS Registry Number:13434-24-7 Formula:Mn[OOCCH(C2H5)C4H9]2 EINECS Number:none Chemical Family:metal carboxylate Synonym:2-Ethylhexanoic acid, manganese +2 salt
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound13434-24-740%0.2mg/m3 (as Mn)5mg/m3 (as Mn) mineral spirits64475-85-060%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed or inhaled. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:Causes mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Vapor is irritating to the nose, mucous membranes and respiratory tract, and cause drowsiness. Ingestion:No information available on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Prolonged exposure to manganese containing dust may produce manganese pneumonitis and manganese Chronic Health Affects:poisoning. Symptoms include sleepiness, weakness and emotional disturbances. Equivocal studies have shown manganese may decrease fertility in men. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Flammable. No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite or other suitable chemical adsorbent. The residue can be swept up Spill and Leak Procedures: and properly disposed of. SECTION 7: Handling and Storage Handling and Storage:Store in a tightly sealed container. Handle the material in a ventilated area. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:dark liquid Molecular Weight:341.35 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:mild organic odor Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable liquid Hazardous Polymerization:none Conditions to Avoid:exposure to excessive heat or an ignition source. Incompatibility:strong oxidizing agents Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, and manganese oxides. SECTION 11: Toxicological Information No information available on the title compound. For mineral spirits: Oral (rat); LD50: >34600mg/kg. RTECS Data: Inhalation (rat); LC50: >21400mg/m3/hr. Intraperitoneal (rat); LDLo: 8560 mg/kg. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Flammable liquids, N.O.S. Hazard Class (CFR):3 Additional Hazard Class (CFR):NA Packaging Group (CFR):III UN ID Number (CFR):UN# 1993 Shipping Name (IATA):Flammable liquid, N.O.S. Hazard Class (IATA):3 Additional Hazard Class (IATA):NA Packaging Group (IATA):III UN ID Number (IATA):UN# 1993 SECTION 15: Regulatory Information TSCA:listed on the TSCA inventory SARA (Title 313):Title compound: See category code N450 for reporting Second Ingredient:not listed on the TSCA inventory SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 1、急性毒性：主要的刺激性影响：强烈的刺激皮肤和粘膜，没有已知的敏化影响。 生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境
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| 危害码 (欧洲) | Xn: Harmful; |
|---|---|
| 风险声明 (欧洲) | R10 |
| 安全声明 (欧洲) | 16-36/37/39 |
| 危险品运输编码 | UN 1993 |
| 包装等级 | III |