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| 中文名 | 二(五甲基环戊二烯基)六氟磷酸钴(III) |
|---|---|
| 英文名 | bis(pentamethylcyclopentadienyl)cobalt(iii) hexafluorophosphate |
| 中文别名 | 双(五甲基环辛二烯)铬六氟磷酸 |
| 英文别名 |
DECAMETHYLCOBALTOCENIUM HEXAFLUOROPHOSPHATE
MFCD00269818 decamethylcobalticinium hexafluorophosphate decamethylcobaltocinium hexafluorophosphate |
| 熔点 | 305ºC |
|---|---|
| 分子式 | C20H30CoF6P |
| 分子量 | 474.35000 |
| 精确质量 | 474.13200 |
| PSA | 13.59000 |
| LogP | 9.32640 |
| 储存条件 | 存放在密封容器内，并放在阴凉，干燥处。储存的地方必须远离氧化剂。避免接触水源。 |
| 稳定性 | 远离氧化物，水。 |
| 计算化学 | 1、 疏水参数计算参考值（XlogP）： 2、 氢键供体数量： 3、 氢键受体数量： 4、 可旋转化学键数量： 5、 拓扑分子极性表面积（TPSA）： 6、 重原子数量： 7、 表面电荷： 8、 复杂度： 9、 同位素原子数量：0 10、 确定原子立构中心数量：0 11、 不确定原子立构中心数量：0 12、 确定化学键立构中心数量：0 13、 不确定化学键立构中心数量：0 14、 共价键单元数量：1 |
| 更多 | 1. 性状：固体。 2. 密度（g/mL,25/4℃）：未确定 3. 相对蒸汽密度（ g/mL, 空气 =1 ）：未确定 4. 熔点（ ºC ）：3055. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 。 |
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Section 1: Product Identification Chemical Name:Bis(pentamethylcyclopentadienyl)cobalticinium hexafluorophosphate, 98% CAS Registry Number:79973-42-5 Formula:[(CH3)5C5]2Co+PF6- EINECS Number:none Chemical Family:metallocene Synonym:none
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound79973-42-5100%0.02mg/m3 (as Co)no data Section 3: Hazards Identification Causes irritation of eyes, skin, and respiratory tract. May cause lung disease, polycythemia, congestive failure, Emergency Overview: and enlargement of the thyroid. Limited evidence of a carcinogenic effect. Primary Routes of Exposure:Skin and eyes, ingestion and dust inhalation. Eye Contact:Causes irritation, redness, and pain. Skin Contact:May cause dermatitis. Causes irritation to skin. Symptoms include redness, itching, and pain. Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath, nausea, Inhalation: respiratory hypersensitivity, asthma. Causes abdominal pain, nausea, vomiting, flushing of the face and ears, mild hypo tension, rash, and ringing Ingestion: in the ears. Irritating to skin, eyes and respiratory tract. Causes abdominal pain, nausea, vomiting, coughing, and Acute Health Affects: shortness of breath. Repeated oral administration of cobalt salts may reduce thyroid activity, cause blood disease, and damage Chronic Health Affects:kidney, heart and lungs. Prolonged or repeated skin exposure may cause dermatitis. Limited evidence of a carcinogenic effect. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry area away from heat and direct sunlight. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow to orange pwdr. Molecular Weight:474.35 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:slightly soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:Oxidizing agent and halogens Decomposition Products:Cobalt oxide, phosphorus pentoxide, and hydrogen fluoride. SECTION 11: Toxicological Information RTECS Data:No specific information available on this product. Carcinogenic Effects:Possible carcinogen (as Co) Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound: See category N096 for reporting. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。
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| 危害码 (欧洲) | C: Corrosive; |
|---|---|
| 风险声明 (欧洲) | R14 |
| 安全声明 (欧洲) | 26-27-36/37/39-45 |
| 危险品运输编码 | UN 3260 8/PG 3 |
| 包装等级 | III |
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79973-42-5 |
| 文献：Chemical Communications, , # 33 p. 3467 - 3469 |
