| 中文名 | 3-(七氟异丙氧基)丙基三氯硅烷 |
|---|---|
| 英文名 | trichloro-[3-(1,1,1,2,3,3,3-heptafluoropropan-2-yloxy)propyl]silane |
| 中文别名 |
3-八氟异丙氧基丙基三氯硅烷
(3-七氟异丙氧基)丙基三氯硅烷 |
| 英文别名 |
EINECS 239-589-6
propylheptafluoroisobutylethertrichlorosilane Trichloro{3-[(1,1,1,2,3,3,3-heptafluoropropan-2-yl)oxy]propyl}silane MFCD00045135 Trichloro(3-(1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethoxy)propyl)silane Trichloro{3-[(1,1,1,2,3,3,3-heptafluoro-2-propanyl)oxy]propyl}silane 3-(Heptafluoroisopropoxy)propyltrichlorosilane Silane, trichloro[3-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethoxy]propyl]- PC4497 |
| 密度 | 1.5±0.1 g/cm3 |
|---|---|
| 沸点 | 217.1±0.0 °C at 760 mmHg |
| 熔点 | <0ºC |
| 分子式 | C6H6Cl3F7OSi |
| 分子量 | 361.545 |
| 闪点 | 81.7±0.0 °C |
| 精确质量 | 359.914185 |
| PSA | 9.23000 |
| LogP | 7.61 |
| 蒸汽压 | 0.2±0.4 mmHg at 25°C |
| 折射率 | 1.379 |
Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 14 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Reacts violently with water. Causes burns.Water-reactive. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. Inhalation: May cause respiratory tract irritation. Inhalation of vapors causes irritation of the mucous membranes. Causes corrosive action on the mucous membranes. Chronic: No information found. Chronic inhalation may cause spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Antidote: None reported. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Use water spray to keep fire-exposed containers cool. Combustible liquid. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May ignite or explode on contact with steam or moist air. Containers may explode when heated. Extinguishing Media: Use dry sand or earth to smother fire. Do NOT use water directly on fire. In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Contact professional fire-fighters immediately. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Do not expose spill to water. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Do not allow water to get into the container because of violent reaction. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not ingest or inhale. Use and store under nitrogen. Do not allow contact with water. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep from contact with moist air and steam. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Corrosives area. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 15538-93-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 39 deg C @ .50mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 81 deg C ( 177.80 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.4970g/cm3 Molecular Formula: C6H6Cl3F7OSi Molecular Weight: 361.55 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Combines vigorously or explosively with water. Conditions to Avoid: Incompatible materials, ignition sources, excess heat, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents, water. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride gas, silicon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 15538-93-9 unlisted. LD50/LC50: Not available. Carcinogenicity: (3-(Heptafluoroisopropoxy)propyl)trichlorosilane - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: WATER-REACTIVE LIQUID, CORROSIVE, N.O.S.* Hazard Class: 4.3 (8) UN Number: 3129 Packing Group: I IMO Shipping Name: WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. Hazard Class: 4.3 (8) UN Number: 3129 Packing Group: I RID/ADR Shipping Name: WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. Hazard Class: 4.3 (8) UN Number: 3129 Packing group: I Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 14 Reacts violently with water. R 34 Causes burns. Safety Phrases: S 8 Keep container dry. S 25 Avoid contact with eyes. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 27 Take off immediately all contaminated clothing. S 28A After contact with skin, wash immediately with plenty of water. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 15538-93-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 15538-93-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 15538-93-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | C: Corrosive; |
|---|---|
| 风险声明 (欧洲) | R34 |
| 安全声明 (欧洲) | 26-36/37/39-45-27 |
| 危险品运输编码 | UN 2987 |
| 包装等级 | II |
| 海关编码 | 2931900090 |
| 海关编码 | 2931900090 |
|---|---|
| 中文概述 | 2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0% |
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |