苯基三氯硅烷

苯基三氯硅烷用途

【用途一】
用于生产含苯基的硅油、硅树脂
【用途二】
用于有机硅化合物的合成
【用途三】
用作硅油、硅树脂的原料，也用于制漆工业
【用途四】
用来生产苯基硅树脂，用于涂料工业。
【用途五】
用于合成有机硅树脂及含苯基硅化合物中，是有机硅最重要的单体之一。用来生产苯基硅树脂，用于涂料工业。

苯基三氯硅烷名称

[ CAS 号 ]:
98-13-5

[ 中文名 ]:
苯基三氯硅烷

[ 英文名 ]:
Trichlorophenylsilane

[中文别名 ]:

[英文别名 ]:

MFCD00000479
phenyl trichlorosilane
Phenyltrichlorosilane
Trichloro(phenyl)silane
UNII:M7199JL06M
Trichlorophenylsilane
Benzene, (trichlorosilyl)-
EINECS 202-640-8

苯基三氯硅烷物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
201.0±9.0 °C at 760 mmHg

[ 熔点 ]:
-127°C

[ 分子式 ]:
C₆H₅Cl₃Si

[ 分子量 ]:
211.548

[ 闪点 ]:
87.5±13.4 °C

[ 精确质量 ]:
209.922607

[ LogP ]:
5.94

[ 外观性状 ]:
无色透明液体

[ 蒸汽压 ]:
0.4±0.4 mmHg at 25°C

[ 折射率 ]:
1.536

[ 储存条件 ]:
库房通风低温干燥,与碱、氧化剂、酸分开存放

[ 水溶解性 ]:
reacts

苯基三氯硅烷MSDS

苯基三氯硅烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: VV6650000

CHEMICAL NAME :: Silane, trichlorophenyl-

CAS REGISTRY NUMBER :: 98-13-5

BEILSTEIN REFERENCE NO. :: 0508730

LAST UPDATED :: 199806

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C6-H5-Cl3-Si

MOLECULAR WEIGHT :: 211.55

WISWESSER LINE NOTATION :: G-SI-GGR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1228,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2390 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 330 mg/m3/2H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 3,23,1961

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04051

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 890 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84666 No. of Facilities: 8 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 272 (estimated)

苯基三氯硅烷安全信息

[ 符号 ]:

GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H312-H314-H330

[ 补充危害声明 ]:
Corrosive to the respiratory tract., Reacts violently with water.

[ 警示性声明 ]:
P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P233

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R21;R34

[ 安全声明 (欧洲) ]:
S23-S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 1804 8/PG 2

[ WGK德国 ]:
1

[ RTECS号 ]:
VV6650000

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
2931900090

苯基三氯硅烷合成路线

苯基三氯硅烷上下游产品

苯基三氯硅烷上游产品

苯基三氯硅烷下游产品

苯基三氯硅烷制备

氯苯与硅粉在铜催化下一步合成得到粗单体，组成一般为一苯基三氯硅烷30%，二苯基二氯硅烷8%，通过精馏将两者分离。原料消耗定额：硅粉（96%）290kg/t、氯化亚铜（95%）179kg/t、氯化苯（98%）2487kg/t。

苯基三氯硅烷海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

苯基三氯硅烷文献

Cleavage of the C-Si bond in Trifluoro (phenyl) silane with Aliphatic Alcohols.

Russ. J. Gen. Chem. 75(12) , 1927-1929, (2005)

Syntheses and structural analyses of 1, 3-diphenyldisiloxanes as a building block of silsesquioxanes.

Bull. Chem. Soc. Jpn. 76(10) , 1983-19887, (2003)

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