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内吸磷-S-甲基

内吸磷-S-甲基名称

[ CAS 号 ]:
919-86-8

[ 中文名 ]:
甲基内吸磷

[ 英文名 ]:
demeton-S-methyl

[中文别名 ]:

内吸磷-S-甲基

[英文别名 ]:

Methyl isosystox
Metaisosystox
DEMETON-S-METHYL
S-2-ethylthioethyl O,O-dimethyl phosphorothioate
MFCD00055464
Thiometon oxon
Demetox
Metasystox J
O,O-dimethyl S-2-ethylthioethyl phosphorothioate
methylmercaptophos thiol

内吸磷-S-甲基物理化学性质

[ 密度 ]:
1.197g/cm3

[ 沸点 ]:
287.4ºC at 760 mmHg

[ 熔点 ]:
<25℃

[ 分子式 ]:
C₆H₁₅O₃PS₂

[ 分子量 ]:
230.28500

[ 闪点 ]:
2ºC

[ 精确质量 ]:
230.02000

[ PSA ]:
95.94000

[ LogP ]:
2.87360

[ 折射率 ]:
1.496

[ 储存条件 ]:
库房低温,通风,干燥,与食品原料分开存放

内吸磷-S-甲基MSDS

内吸磷-S-甲基毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TG1750000

CHEMICAL NAME :: Phosphorothioic acid, S-(2-(ethylthio)ethyl) O,O-dimethyl ester

CAS REGISTRY NUMBER :: 919-86-8

BEILSTEIN REFERENCE NO. :: 1707311

LAST UPDATED :: 199703

DATA ITEMS CITED :: 14

MOLECULAR FORMULA :: C6-H15-O3-P-S2

MOLECULAR WEIGHT :: 230.30

WISWESSER LINE NOTATION :: 2S2SPO&O1&O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 30 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 500 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 85 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 7500 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 65 mg/kg

TOXIC EFFECTS :: Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other esterases

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 110 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 12500 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TEST SYSTEM :: Insect - Drosophila melanogaster

DOSE/DURATION :: 80 ppm

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 28,405,1975 *** REVIEWS *** TOXICOLOGY REVIEW DTTIAF Deutsche Tieraerztliche Wochenschrift. (Hanover, Fed. Rep. Ger.) V.1-77, 1893-1970. Volume(issue)/page/year: 80,485,1973 TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 63,1,1976

内吸磷-S-甲基安全信息

[ 符号 ]:

GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311-H411

[ 警示性声明 ]:
P273-P280-P301 + P310 + P330-P302 + P352 + P312-P391-P501

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T,N,Xn,F

[ 风险声明 (欧洲) ]:
24/25-51/53-36-20/21/22-11

[ 安全声明 (欧洲) ]:
S26;S36/S37

[ 危险品运输编码 ]:
UN 3018

[ RTECS号 ]:
TG1750000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1(a)

内吸磷-S-甲基合成路线

内吸磷-S-甲基文献

Mutagenesis of organophosphorus hydrolase to enhance hydrolysis of the nerve agent VX.

Biochem. Biophys. Res. Commun. 279(2) , 516-9, (2000)

Organophosphorus hydrolase (OPH) is capable of hydrolyzing a wide variety of organophosphorus pesticides and chemical warfare agents. However, the hydrolytic activity of OPH against the warfare agent ...

[First drafts of the Environmental Health Criteria (EHC) circulated for comments by IPCS in 1995-1996].

Eisei Shikenjo Hokoku. (114) , 95-8, (1996)

Genes coding for cytochrome P450 are regulated by endogenous hormones such as the growth hormone, corticosteroids, thyroid, and sex hormones. Secretion of these hormones is regulated by the respective...

[The decrement-increment phenomenon in disorders of neuromuscular transmission by inhibition of acetylcholinesterase].

EEG EMG Z. Elektroenzephalogr. Elektromyogr. Verwandte Geb. 20(1) , 28-33, (1989)

Repetitive stimulation of the median nerve elicited a so far unknown course of the muscle action potentials in four patients with organophosphate intoxications. The amplitude of the initial muscle act...

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