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氟硅唑

氟硅唑用途

Flusilazole (DPX-H6573) 是一种有机硅烷杀菌剂 (fungicide),具有广谱抗真菌作用。Flusilazole 具有治疗和预防作用,建议用于农业和园艺。

氟硅唑名称

[ CAS 号 ]:
85509-19-9

[ 中文名 ]:
氟硅唑

[ 英文名 ]:
Flusilazole

[中文别名 ]:

[英文别名 ]:

Caswell No. 419K
T5NN DNJ A1-SI-1&R DF&R DF
Fluzilazol
Sanction
Flusilazol
Punch
Olymp
Flusilazole
UNII-F3WG2VVD87
MFCD01076615

氟硅唑生物活性

[ 描述 ]:

Flusilazole (DPX-H6573) 是一种有机硅烷杀菌剂 (fungicide),具有广谱抗真菌作用。Flusilazole 具有治疗和预防作用,建议用于农业和园艺。

[ 相关类别 ]:

研究领域 >> 感染

信号通路 >> 抗感染 >> 真菌

[参考文献]

[1]. D Fabio Mercado, et al. Reaction Kinetics and Mechanisms of Organosilicon Fungicide Flusilazole With Sulfate and Hydroxyl Radicals. Chemosphere. 2018 Jan;190:327-336.

氟硅唑物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
392.5±52.0 °C at 760 mmHg

[ 熔点 ]:
51-53ºC

[ 分子式 ]:
C₁₆H₁₅F₂N₃Si

[ 分子量 ]:
315.393

[ 闪点 ]:
191.2±30.7 °C

[ 精确质量 ]:
315.100342

[ PSA ]:
30.71000

[ LogP ]:
3.84

[ 外观性状 ]:
白色固体

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.563

[ 储存条件 ]:
0-6°C

氟硅唑MSDS

详细MSDS(安全技术说明书)

氟硅唑毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XZ4105000

CHEMICAL NAME :: 1H-1,2,4-Triazole, 1-((bis(4-fluorophenyl)methylsilyl)methyl)-

CAS REGISTRY NUMBER :: 85509-19-9

LAST UPDATED :: 199710

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C16-H15-F2-N3-Si

MOLECULAR WEIGHT :: 315.43

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 674 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PBCDDQ Proceedings-British Crop Protection Conference-Pests and Diseases. (British Crop., Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1977- Volume(issue)/page/year: -,413,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PBCDDQ Proceedings-British Crop Protection Conference-Pests and Diseases. (British Crop., Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1977- Volume(issue)/page/year: -,413,1984

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: >5 gm/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C142,1991

氟硅唑安全信息

[ 符号 ]:

GHS07, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H351-H360D-H411

[ 警示性声明 ]:
P201-P273-P281-P308 + P313

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T:Toxic;N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R61;R22;R40;R51/53

[ 安全声明 (欧洲) ]:
S53-S45-S61

[ 危险品运输编码 ]:
UN 2588

[ RTECS号 ]:
XZ4105000

[ 海关编码 ]:
2933990015

氟硅唑制备

氯甲基二氯甲硅烷在低温下与氟苯、丁基锂反应，制得双（4-氟基苯）甲基氯代甲基硅烷，再在极性溶剂中与1，2，4-三唑钠反应，制得氟硅唑

氟硅唑海关

[ 海关编码 ]: 2933990015

[ 中文概述 ]:
2933990015 苄氯三唑醇,戊菌唑,粉唑醇等〔包括联苯三唑醇,腈菌唑,环丙唑醇,烯唑醇,戊唑醇,氟硅唑〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2933990015 3-((1h-1,2,4-triazol-1-yl)methyl)-1-(4-chlorophenyl)-4,4-dimethylpentan-3-ol。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

氟硅唑文献

Real-time 2D separation by LC × differential ion mobility hyphenated to mass spectrometry.

Anal. Bioanal. Chem 402(8) , 2555-64, (2012)

The liquid chromatography-mass spectrometry (LC-MS) analysis of complex samples such as biological fluid extracts is widespread when searching for new biomarkers as in metabolomics. The success of thi...

Effects of two systemic fungicides: Artea (Propiconazole+cyproconazole) and Punch (Flusilazole) on the physiology and the respiratory metabolism of durum wheat (Triticum durum L.).

Commun. Agric. Appl. Biol. Sci. 71(3 Pt B) , 1041-8, (2006)

The present work aimed at the study of the effects of Artea and Punch; two systemic fungicides on durum Wheat (Triticum durum L. cv. GTA dur). Seeds were grown in a medium containing respectively 25, ...

Concentration-response analysis of differential gene expression in the zebrafish embryotoxicity test following flusilazole exposure.

Toxicol. Sci. 127(1) , 303-12, (2012)

The zebrafish embryotoxicity test (ZET) is considered a promising alternative model in predictive toxicology. Currently, morphological assessment of the embryo is the main readout for this assay. Howe...

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氟硅唑