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1,1'-双(二叔丁基膦)二茂铁

1,1'-双(二叔丁基膦)二茂铁名称

[ CAS 号 ]:
84680-95-5

[ 中文名 ]:
1,1-二(二-叔丁基膦基)-二茂铁

[ 英文名 ]:
1,1'-Bis(di-tert-butylphosphino)ferrocene

[中文别名 ]:

[英文别名 ]:

MFCD01630818
1,1'-Bis(di-tert-butylphosphino)ferrocene

1,1'-双(二叔丁基膦)二茂铁物理化学性质

[ 熔点 ]:
73-75ºC

[ 分子式 ]:
C₂₆H₄₄FeP₂

[ 分子量 ]:
474.420

[ 精确质量 ]:
474.226776

[ PSA ]:
27.18000

[ LogP ]:
8.28090

[ 外观性状 ]:
crystal | orange to red

[ 储存条件 ]:
存放于惰性气体之中;避免空气

[ 水溶解性 ]:
Insoluble in water.

1,1'-双(二叔丁基膦)二茂铁MSDS

1,1'-双(二叔丁基膦)二茂铁安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

1,1'-双(二叔丁基膦)二茂铁合成路线

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1,1'-双(二叔丁基膦)二茂铁文献

Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline.

J. Org. Chem. 71 , 1969, (2006)

The inter- and intramolecular couplings of unactivated alkenes to 3,4-dihydroquinazolines with a Rh(I) catalyst are reported. Coupling between olefins and NH-3,4-dihydroquinazoline was found to occur ...

A convenient one-pot procedure to afford bicyclic molecules by stereospecific iron carbonyl mediated [6 + 2] ene-type cyclization: a possible approach to gelsemine.

J. Am. Chem. Soc. 125 , 13326, (2003)

A convenient one-pot procedure to prepare angularly substituted bicyclic and tricyclic molecules with excellent diastereoselectivity in good yield was developed, by Fe(CO)5 promoted cyclization. Three...

Sergeyev, S.; Hesse, M.

Synlett 8 , 1313, (2002)

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