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N,N-二乙基-1,5-二氢-2,4,3-苯并二氧杂磷平-3-胺

名称

[ CAS 号 ]:
82372-35-8

[ 中文名 ]:
3-(二乙氨基)-1,5-二氢-2,4,3-苯并二噁磷杂庚英

[ 英文名 ]:
o-Xylylene N,N-Diethylphosphoramidite

[中文别名 ]:

o-亚二甲苯基N,N-二乙基亚磷酰胺

[英文别名 ]:

o-xylylene-N,N-diethylphosphoramidite
MFCD00192025
o-Xylylene N,N-Diethylphosphoramidite

物理化学性质

[ 密度 ]:
1.11 g/mL at 20ºC(lit.)

[ 沸点 ]:
255.3±30.0 °C at 760 mmHg

[ 分子式 ]:
C₁₂H₁₈NO₂P

[ 分子量 ]:
239.251

[ 闪点 ]:
108.2±24.6 °C

[ 精确质量 ]:
239.107513

[ PSA ]:
35.29000

[ LogP ]:
2.42

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
n20/D 1.541(lit.)

[ 储存条件 ]:
2-8℃

安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ 危险品运输编码 ]:
NA 1993 / PGIII

合成路线

详细合成路线

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文献

A scalable synthesis of the IP7 isomer, 5-PP-Ins(1,2,3,4,6)P5.

Org. Lett. 11(7) , 1551-1554, (2009)

The phosphorylated inositol diphosphates, including the diphosphoinositol pentakisphosphate regioisomers, play critical roles in signal transduction and cellular regulation. In particular, the IP(7) i...

Synergistic inhibition of human Synergistic inhibition of human α-1, 3-fucosyltransferase V. Qiao L, et al

J. Am. Chem. Soc. 118(33) , 7653-7662, (1996)

Utilization of O-xylylene N,N-diethylphosphoramidite for the synthesis of phosphoric diesters. Watanabe Y, et al

Tetrahedron Lett. 33(10) , 1313-1316, (1992)

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