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硫酸亚汞

硫酸亚汞用途

【用途一】
用于标准电池的制造
【用途二】
制造电池。

硫酸亚汞名称

[ CAS 号 ]:
7783-36-0

[ 中文名 ]:
硫酸亚汞

[ 英文名 ]:
Mercurous sulfate

[英文别名 ]:

mercury(1+),sulfate
MFCD00016138
EINECS 231-993-0

硫酸亚汞物理化学性质

[ 密度 ]:
7.56 g/mL at 25 °C(lit.)

[ 分子式 ]:
Hg₂O₄S

[ 分子量 ]:
497.24300

[ 精确质量 ]:
499.89300

[ PSA ]:
88.64000

[ 储存条件 ]:
库房通风低温干燥,与食品分开储运

[ 水溶解性 ]:
每100毫升水中的溶解克数: 4.277×10-2/20℃

硫酸亚汞MSDS

详细MSDS(安全技术说明书)

硫酸亚汞毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: OX0480000

CHEMICAL NAME :: Mercury(I) sulfate

CAS REGISTRY NUMBER :: 7783-36-0

LAST UPDATED :: 199712

DATA ITEMS CITED :: 26

MOLECULAR FORMULA :: O4-S.2Hg

MOLECULAR WEIGHT :: 497.24

WISWESSER LINE NOTATION :: .HG2.S-O4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 205 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1175 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 152 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 11500 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 5600 mg/kg

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04883 *** REVIEWS *** ACGIH TLV-TWA 0.025 mg(Hg)/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.05 mg(Hg)/m3 DTLWS* "Documentation of the Threshold Limit Values for Substances in Workroom Air," Supplements. For publisher information, see 85INA8. Volume(issue)/page/year: 3,22,1973 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.05 mg(Hg)/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.05 mg(Hg)/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-FINLAND:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-FRANCE:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-GERMANY:TWA 0.01 ppm (0.1 mg(Hg)/m3) JAN 1993 OEL-HUNGARY:TWA 0.02 mg(Hg)/m3;STEL 0.04 mg(Hg)/m3 JAN 1993 OEL-JAPAN:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.05 mg(Hg)/m3;STEL 0.15 mg(Hg)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-POLAND:TWA 0.01 mg(Hg)/m3 JAN 1993 OEL-RUSSIA:TWA 0.05 mg(Hg)/m3;STEL 0.01 mg(Hg)/m3 JAN 1993 OEL-SWEDEN:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-THAILAND:STEL 0.05 mg(Hg)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.05 mg(Hg)/m3;STEL 0.15 mg(Hg)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO MERCURY, ARYL AND INORGANIC-air:CL 0.1 mg/m3 (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

硫酸亚汞安全信息

[ 符号 ]:

GHS06, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H300 + H310 + H330-H373-H410

[ 警示性声明 ]:
Missing Phrase - N15.00950417-P260-P262-P280-P302 + P352 + P310-P304 + P340 + P310

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T+,N

[ 风险声明 (欧洲) ]:
26/27/28-33-50/53

[ 安全声明 (欧洲) ]:
S13-S28-S45-S60-S61

[ 危险品运输编码 ]:
UN 1645 6.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
OX0480000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1(a)

硫酸亚汞制备

1.将汞与浓硫酸反应即可制得硫酸亚汞。将一份纯净的汞加入到0.5～1份的浓硫酸中，并在通风柜中加热使其发生反应，当差不多有一半汞已转变为固体盐时停止加热。将未反应的汞倒出，所生成的盐用少量冷水洗涤后干燥。

2.将稀硫酸加到硝酸亚汞的溶液中可沉淀出硫酸亚汞。向硝酸亚汞溶液中加入稀硫酸直至Hg2+2沉淀完全为止，用玻璃砂芯漏斗过滤出沉淀，并用少量的冷水洗涤，干燥后即可。

硫酸亚汞文献

Low temperature catalytic conversion of methane to methanol by barium sulfate nanotubes supporting sulfates: Pt(SO4)2, HgSO4, Ce(SO4)2 and Pb(SO4)2.

Chem. Commun. (Camb.) (17) , 2238-40, (2005)

Barium sulfate nanotubes perform excellently in supporting sulfates (Pt(SO4)2, HgSO4, Ce(SO4)2 and Pb(SO4)2) for low temperature catalytic conversion of methane to methanol under strongly acidic condi...

[Morphological manifestations of the toxic effect of uni- and bivalent mercury compounds during repeated peroral administration].

Vrach. Delo (9) , 107-9, (1983)

[A case of granulomatous reaction to tattooing].

Minerva Chir. 42(8) , 747-9, (1987)

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