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1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯

1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯名称

[ CAS 号 ]:
77086-38-5

[ 中文名 ]:
1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯

[ 英文名 ]:
1-(tert-Butyldimethylsilyloxy)-1-methoxyethene

[英文别名 ]:

MFCD02683524
TBS-methoxyethene

1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯物理化学性质

[ 密度 ]:
0.863 g/mL at 25ºC(lit.)

[ 沸点 ]:
62ºC9 mm Hg(lit.)

[ 分子式 ]:
C₉H₂₀O₂Si

[ 分子量 ]:
188.33900

[ 闪点 ]:
125 °F

[ 精确质量 ]:
188.12300

[ PSA ]:
18.46000

[ LogP ]:
3.12580

[ 外观性状 ]:
液体;Colorless to Almost colorless clear liquid

[ 折射率 ]:
n20/D 1.429(lit.)

[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (分解)

1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯MSDS

1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯安全信息

[ 符号 ]:

GHS02

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F+

[ 风险声明 (欧洲) ]:
10

[ 危险品运输编码 ]:
UN 1993 3/PG 3

[ 危险类别 ]:
3.0

[ 海关编码 ]:
2931900090

1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯合成路线

1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯上下游产品

1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯上游产品

1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯下游产品

1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

1-(叔丁基二甲基硅氧基)-1-甲氧基乙烯文献

New indenyl phosphinooxazoline complexes of iron and their catalytic activity in the Mukaiyama aldol reaction. Lenze M, et al.

Tetrahedron Lett. 51(21) , 2855-2858, (2010)

Recent developments in the syntheses of the epothilones and related analogues. Watkins EB, et al.

European J. Org. Chem. 18 , 4071-4084, (2006)

Enantioselective addition of ketene silyl acetals to nitrones catalyzed by chiral titanium complexes. Synthesis of optically active ß-amino acids. Murahashi SI, et al.

J. Am. Chem. Soc. 124(12) , 2888-2889, (2002)

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