氟化乙烯

氟化乙烯用途

1.主要用于生产聚氟乙烯，也用于其他树脂的合成。

2.主要用于聚合制聚氟乙烯。

氟化乙烯名称

[ CAS 号 ]:
75-02-5

[ 中文名 ]:
氟化乙烯

[ 英文名 ]:
Vinyl fluoride

[中文别名 ]:

氟乙烯

[英文别名 ]:

EINECS 200-832-6
MFCD00042113
Vinyl fluoride
Monofluoroethylene
F1U1
Ethylene,fluoro
Fluoroethylene
Fluoroethene
1-fluoroethylene
fluoro-ethylene

氟化乙烯物理化学性质

[ 密度 ]:
0.7±0.1 g/cm3

[ 沸点 ]:
-73.5±9.0 °C at 760 mmHg

[ 熔点 ]:
-160,5°C

[ 分子式 ]:
C₂H₃F

[ 分子量 ]:
46.044

[ 闪点 ]:
-91.0±11.9 °C

[ 精确质量 ]:
46.021877

[ LogP ]:
1.18

[ 蒸汽压 ]:
18399.8±0.1 mmHg at 25°C

[ 折射率 ]:
1.289

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开存放

氟化乙烯MSDS

详细MSDS(安全技术说明书)

氟化乙烯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: YZ7351000

CHEMICAL NAME :: Vinyl fluoride

CAS REGISTRY NUMBER :: 75-02-5

BEILSTEIN REFERENCE NO. :: 1731574

LAST UPDATED :: 199710

DATA ITEMS CITED :: 16

MOLECULAR FORMULA :: C2-H3-F

MOLECULAR WEIGHT :: 46.05

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC - Lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >80 pph/12.5H

TOXIC EFFECTS :: Behavioral - altered sleep time (including change in righting reflex) Behavioral - changes in motor activity (specific assay) Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2000 ppm/6H/13W-I

TOXIC EFFECTS :: Liver - other changes Kidney, Ureter, Bladder - other changes in urine composition

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 20000 ppm/6H/13W-I

TOXIC EFFECTS :: Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Liver - other changes Kidney, Ureter, Bladder - other changes in urine composition

TYPE OF TEST :: Morphological transformation

MUTATION DATA

TEST SYSTEM :: Rodent - mouse

REFERENCE :: EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 19(Suppl 20),5,1992 *** REVIEWS *** IARC Cancer Review:Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 63,467,1995 IARC Cancer Review:Animal No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 39,147,1986 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 39,147,1986 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 63,467,1995 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987 IARC Cancer Review:Group 2A IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 63,467,1995 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO VINYL FLUORIDE-air:use 29 CFR 1910.1017 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

氟化乙烯安全信息

[ 危害码 (欧洲) ]:
F

[ 风险声明 (欧洲) ]:
R12;R40

[ 安全声明 (欧洲) ]:
S9-S16-S23-S36/37/39

[ 危险品运输编码 ]:
1860

[ 危险类别 ]:
2.1

氟化乙烯合成路线

详细合成路线

氟化乙烯上下游产品

氟化乙烯上游产品

氟化乙烯下游产品

氟化乙烯制备

1．乙炔法　采用乙炔与氟化氢催化加成的方法。

2．氯乙烯法　其反应式如下：